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Bis(2,2′,2′′-nitrilotriacetamide-κ(3) O,N,O′)cobalt(II) dinitrate tetrahydrate
In the centrosymmetric title compound, [Co(C(6)H(12)N(4)O(3))(2)](NO(3))(2)·4H(2)O, the Co(II) ion, lying on an inversion center, is O,N,O′-chelated by two nitrilotriacetamide molecules, forming a distorted octahedral geometry. In the crystal, extensive O—H⋯O and N—H⋯O hydrogen bonds link the com...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684886/ https://www.ncbi.nlm.nih.gov/pubmed/23794988 http://dx.doi.org/10.1107/S1600536813012968 |
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author | Ran, Jing-Wen Pei, Jun |
author_facet | Ran, Jing-Wen Pei, Jun |
author_sort | Ran, Jing-Wen |
collection | PubMed |
description | In the centrosymmetric title compound, [Co(C(6)H(12)N(4)O(3))(2)](NO(3))(2)·4H(2)O, the Co(II) ion, lying on an inversion center, is O,N,O′-chelated by two nitrilotriacetamide molecules, forming a distorted octahedral geometry. In the crystal, extensive O—H⋯O and N—H⋯O hydrogen bonds link the complex cations, nitrate anions and lattice water molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3684886 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848862013-06-21 Bis(2,2′,2′′-nitrilotriacetamide-κ(3) O,N,O′)cobalt(II) dinitrate tetrahydrate Ran, Jing-Wen Pei, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Co(C(6)H(12)N(4)O(3))(2)](NO(3))(2)·4H(2)O, the Co(II) ion, lying on an inversion center, is O,N,O′-chelated by two nitrilotriacetamide molecules, forming a distorted octahedral geometry. In the crystal, extensive O—H⋯O and N—H⋯O hydrogen bonds link the complex cations, nitrate anions and lattice water molecules into a three-dimensional network. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3684886/ /pubmed/23794988 http://dx.doi.org/10.1107/S1600536813012968 Text en © Ran and Pei 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ran, Jing-Wen Pei, Jun Bis(2,2′,2′′-nitrilotriacetamide-κ(3) O,N,O′)cobalt(II) dinitrate tetrahydrate |
title | Bis(2,2′,2′′-nitrilotriacetamide-κ(3)
O,N,O′)cobalt(II) dinitrate tetrahydrate |
title_full | Bis(2,2′,2′′-nitrilotriacetamide-κ(3)
O,N,O′)cobalt(II) dinitrate tetrahydrate |
title_fullStr | Bis(2,2′,2′′-nitrilotriacetamide-κ(3)
O,N,O′)cobalt(II) dinitrate tetrahydrate |
title_full_unstemmed | Bis(2,2′,2′′-nitrilotriacetamide-κ(3)
O,N,O′)cobalt(II) dinitrate tetrahydrate |
title_short | Bis(2,2′,2′′-nitrilotriacetamide-κ(3)
O,N,O′)cobalt(II) dinitrate tetrahydrate |
title_sort | bis(2,2′,2′′-nitrilotriacetamide-κ(3)
o,n,o′)cobalt(ii) dinitrate tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684886/ https://www.ncbi.nlm.nih.gov/pubmed/23794988 http://dx.doi.org/10.1107/S1600536813012968 |
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