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catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3) O (1),N:O (2);κ(3) O (2):N,O (1)}] iodide]
In the title one-dimensional coordination polymer, {[Mn(C(10)H(12)NO(3))(2)]I}(n), the potentially tetradentate (O,O,O,N) 2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenol (H(2) L) ligands are mono-deprotonated (as HL (−)) and coordinated by the metal ions in a tridentate chelate-bridging fash...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684887/ https://www.ncbi.nlm.nih.gov/pubmed/23794989 http://dx.doi.org/10.1107/S1600536813012695 |
Sumario: | In the title one-dimensional coordination polymer, {[Mn(C(10)H(12)NO(3))(2)]I}(n), the potentially tetradentate (O,O,O,N) 2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenol (H(2) L) ligands are mono-deprotonated (as HL (−)) and coordinated by the metal ions in a tridentate chelate-bridging fashion [2.01(1)1(1)1(2)]. The Mn(III) atom possesses a distorted trans-MnO(4)N(2) octahedral coordination environment. The bridging ligands lead to [010]-chain polymeric cations {[Mn(HL)(2)](+)}(n) in the crystal. The charge-balancing iodide ions are disordered over two sites in a 0.690 (2):0.310 (2) ratio and a weak O—H⋯I hydrogen bond occurs. The crystal studied was found to be a racemic twin. |
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