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catena-Poly[[manganese(III)-bis­{μ-2-[(2-hy­droxy­eth­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(3) O (1),N:O (2);κ(3) O (2):N,O (1)}] iodide]

In the title one-dimensional coordination polymer, {[Mn(C(10)H(12)NO(3))(2)]I}(n), the potentially tetra­dentate (O,O,O,N) 2-[(2-hy­droxy­eth­yl)imino­meth­yl]-6-meth­oxy­phenol (H(2) L) ligands are mono-deprotonated (as HL (−)) and coordinated by the metal ions in a tridentate chelate-bridging fash...

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Detalles Bibliográficos
Autores principales: Petrusenko, Svitlana R., Stetsyuk, Oleg M., Omelchenko, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684887/
https://www.ncbi.nlm.nih.gov/pubmed/23794989
http://dx.doi.org/10.1107/S1600536813012695
Descripción
Sumario:In the title one-dimensional coordination polymer, {[Mn(C(10)H(12)NO(3))(2)]I}(n), the potentially tetra­dentate (O,O,O,N) 2-[(2-hy­droxy­eth­yl)imino­meth­yl]-6-meth­oxy­phenol (H(2) L) ligands are mono-deprotonated (as HL (−)) and coordinated by the metal ions in a tridentate chelate-bridging fashion [2.01(1)1(1)1(2)]. The Mn(III) atom possesses a distorted trans-MnO(4)N(2) octa­hedral coordination environment. The bridging ligands lead to [010]-chain polymeric cations {[Mn(HL)(2)](+)}(n) in the crystal. The charge-balancing iodide ions are disordered over two sites in a 0.690 (2):0.310 (2) ratio and a weak O—H⋯I hydrogen bond occurs. The crystal studied was found to be a racemic twin.