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catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3) O (1),N:O (2);κ(3) O (2):N,O (1)}] iodide]
In the title one-dimensional coordination polymer, {[Mn(C(10)H(12)NO(3))(2)]I}(n), the potentially tetradentate (O,O,O,N) 2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenol (H(2) L) ligands are mono-deprotonated (as HL (−)) and coordinated by the metal ions in a tridentate chelate-bridging fash...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684887/ https://www.ncbi.nlm.nih.gov/pubmed/23794989 http://dx.doi.org/10.1107/S1600536813012695 |
| _version_ | 1782273626724106240 |
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| author | Petrusenko, Svitlana R. Stetsyuk, Oleg M. Omelchenko, Irina V. |
| author_facet | Petrusenko, Svitlana R. Stetsyuk, Oleg M. Omelchenko, Irina V. |
| author_sort | Petrusenko, Svitlana R. |
| collection | PubMed |
| description | In the title one-dimensional coordination polymer, {[Mn(C(10)H(12)NO(3))(2)]I}(n), the potentially tetradentate (O,O,O,N) 2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenol (H(2) L) ligands are mono-deprotonated (as HL (−)) and coordinated by the metal ions in a tridentate chelate-bridging fashion [2.01(1)1(1)1(2)]. The Mn(III) atom possesses a distorted trans-MnO(4)N(2) octahedral coordination environment. The bridging ligands lead to [010]-chain polymeric cations {[Mn(HL)(2)](+)}(n) in the crystal. The charge-balancing iodide ions are disordered over two sites in a 0.690 (2):0.310 (2) ratio and a weak O—H⋯I hydrogen bond occurs. The crystal studied was found to be a racemic twin. |
| format | Online Article Text |
| id | pubmed-3684887 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36848872013-06-21 catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3) O (1),N:O (2);κ(3) O (2):N,O (1)}] iodide] Petrusenko, Svitlana R. Stetsyuk, Oleg M. Omelchenko, Irina V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, {[Mn(C(10)H(12)NO(3))(2)]I}(n), the potentially tetradentate (O,O,O,N) 2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenol (H(2) L) ligands are mono-deprotonated (as HL (−)) and coordinated by the metal ions in a tridentate chelate-bridging fashion [2.01(1)1(1)1(2)]. The Mn(III) atom possesses a distorted trans-MnO(4)N(2) octahedral coordination environment. The bridging ligands lead to [010]-chain polymeric cations {[Mn(HL)(2)](+)}(n) in the crystal. The charge-balancing iodide ions are disordered over two sites in a 0.690 (2):0.310 (2) ratio and a weak O—H⋯I hydrogen bond occurs. The crystal studied was found to be a racemic twin. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3684887/ /pubmed/23794989 http://dx.doi.org/10.1107/S1600536813012695 Text en © Petrusenko et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Petrusenko, Svitlana R. Stetsyuk, Oleg M. Omelchenko, Irina V. catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3) O (1),N:O (2);κ(3) O (2):N,O (1)}] iodide] |
| title |
catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3)
O
(1),N:O
(2);κ(3)
O
(2):N,O
(1)}] iodide] |
| title_full |
catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3)
O
(1),N:O
(2);κ(3)
O
(2):N,O
(1)}] iodide] |
| title_fullStr |
catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3)
O
(1),N:O
(2);κ(3)
O
(2):N,O
(1)}] iodide] |
| title_full_unstemmed |
catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3)
O
(1),N:O
(2);κ(3)
O
(2):N,O
(1)}] iodide] |
| title_short |
catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3)
O
(1),N:O
(2);κ(3)
O
(2):N,O
(1)}] iodide] |
| title_sort | catena-poly[[manganese(iii)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ(3)
o
(1),n:o
(2);κ(3)
o
(2):n,o
(1)}] iodide] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684887/ https://www.ncbi.nlm.nih.gov/pubmed/23794989 http://dx.doi.org/10.1107/S1600536813012695 |
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