Tetra­phenyl­phospho­nium [μ(3)-(4-methyl­phen­yl)tellurolato]tris­[tetra­carbonyl­iron(0)]

In the anion of the title compound, (C(24)H(20)P)[Fe(3)(C(7)H(7)Te)(CO)(12)], each Fe(0) atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal–bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl­phenyl group and the Fe(0) atoms in a distorted tetra­...

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Detalles Bibliográficos
Autores principales: Li, Yu-Long, Xie, Bin, Zou, Li-Ke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684888/
https://www.ncbi.nlm.nih.gov/pubmed/23794990
http://dx.doi.org/10.1107/S1600536813013056
Descripción
Sumario:In the anion of the title compound, (C(24)H(20)P)[Fe(3)(C(7)H(7)Te)(CO)(12)], each Fe(0) atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal–bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl­phenyl group and the Fe(0) atoms in a distorted tetra­hedral geometry. The average Te—Fe bond length is 2.574 (4) Å.

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