cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)

The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(C(6)H(5)CN)(2)], exhibits crystallographically imposed centrosymmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner, with two N atoms and two O atoms coordinating to the unique Rh(II)...

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Autores principales: Eagle, Cassandra T., Quarshie, Fredricka, Ketron, Megan E., Atem-Tambe, Nkongho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684889/
https://www.ncbi.nlm.nih.gov/pubmed/23794991
http://dx.doi.org/10.1107/S1600536813012828
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author Eagle, Cassandra T.
Quarshie, Fredricka
Ketron, Megan E.
Atem-Tambe, Nkongho
author_facet Eagle, Cassandra T.
Quarshie, Fredricka
Ketron, Megan E.
Atem-Tambe, Nkongho
author_sort Eagle, Cassandra T.
collection PubMed
description The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(C(6)H(5)CN)(2)], exhibits crystallographically imposed centrosymmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner, with two N atoms and two O atoms coordinating to the unique Rh(II) atom cis to one another. The N(eq)—Rh—Rh—O(eq) torsion angles on the acetamide bridges vary between 1.62 (4) and 1.78 (4)°. The Rh—Rh bond length is 2.4319 (3) Å. The axial nitrile ligand completes the distorted octahedral coordination sphere and shows a non-linear coordination with an Rh—N—C bond angle of 167.14 (15)°, while the N—C bond length is 1.135 (3) Å.
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spelling pubmed-36848892013-06-21 cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh) Eagle, Cassandra T. Quarshie, Fredricka Ketron, Megan E. Atem-Tambe, Nkongho Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(C(6)H(5)CN)(2)], exhibits crystallographically imposed centrosymmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner, with two N atoms and two O atoms coordinating to the unique Rh(II) atom cis to one another. The N(eq)—Rh—Rh—O(eq) torsion angles on the acetamide bridges vary between 1.62 (4) and 1.78 (4)°. The Rh—Rh bond length is 2.4319 (3) Å. The axial nitrile ligand completes the distorted octahedral coordination sphere and shows a non-linear coordination with an Rh—N—C bond angle of 167.14 (15)°, while the N—C bond length is 1.135 (3) Å. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3684889/ /pubmed/23794991 http://dx.doi.org/10.1107/S1600536813012828 Text en © Eagle et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Eagle, Cassandra T.
Quarshie, Fredricka
Ketron, Megan E.
Atem-Tambe, Nkongho
cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_full cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_fullStr cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_full_unstemmed cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_short cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_sort cis-tetra­kis(μ-n-phenyl­acetamidato)-κ(4) n:o;κ(4) o:n-bis­[(benzo­nitrile-κn)rhodium(ii)](rh—rh)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684889/
https://www.ncbi.nlm.nih.gov/pubmed/23794991
http://dx.doi.org/10.1107/S1600536813012828
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