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trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)

In the title compound, trans-[PtCl(2)(C(15)H(15)ClFN(5))(2)], the Pt(II) atom, located on an inversion centre, is coordinated by the purine N atoms of the 2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine ligands and two Cl atoms in a slightly distorted trans-square-planar coordination geom...

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Detalles Bibliográficos
Autores principales: Trávníček, Zdeněk, Štarha, Pavel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684891/
https://www.ncbi.nlm.nih.gov/pubmed/23794993
http://dx.doi.org/10.1107/S1600536813013202
Descripción
Sumario:In the title compound, trans-[PtCl(2)(C(15)H(15)ClFN(5))(2)], the Pt(II) atom, located on an inversion centre, is coordinated by the purine N atoms of the 2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine ligands and two Cl atoms in a slightly distorted trans-square-planar coordination geometry [N—Pt—Cl angles = 89.91 (5) and 90.09 (5)°]. Weak intra­molecular N—H⋯Cl contacts occur. In the crystal, C—H⋯Cl and C—H⋯F contacts, as well as weak π–π stacking inter­actions [centroid–centroid distances = 3.5000 (11) and 3.6495 (12) Å] connect the mol­ecules into a three-dimensional architecture.