trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)

In the title compound, trans-[PtCl(2)(C(15)H(15)ClFN(5))(2)], the Pt(II) atom, located on an inversion centre, is coordinated by the purine N atoms of the 2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine ligands and two Cl atoms in a slightly distorted trans-square-planar coordination geom...

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Detalles Bibliográficos
Autores principales: Trávníček, Zdeněk, Štarha, Pavel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684891/
https://www.ncbi.nlm.nih.gov/pubmed/23794993
http://dx.doi.org/10.1107/S1600536813013202
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author Trávníček, Zdeněk
Štarha, Pavel
author_facet Trávníček, Zdeněk
Štarha, Pavel
author_sort Trávníček, Zdeněk
collection PubMed
description In the title compound, trans-[PtCl(2)(C(15)H(15)ClFN(5))(2)], the Pt(II) atom, located on an inversion centre, is coordinated by the purine N atoms of the 2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine ligands and two Cl atoms in a slightly distorted trans-square-planar coordination geometry [N—Pt—Cl angles = 89.91 (5) and 90.09 (5)°]. Weak intra­molecular N—H⋯Cl contacts occur. In the crystal, C—H⋯Cl and C—H⋯F contacts, as well as weak π–π stacking inter­actions [centroid–centroid distances = 3.5000 (11) and 3.6495 (12) Å] connect the mol­ecules into a three-dimensional architecture.
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spelling pubmed-36848912013-06-21 trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II) Trávníček, Zdeněk Štarha, Pavel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, trans-[PtCl(2)(C(15)H(15)ClFN(5))(2)], the Pt(II) atom, located on an inversion centre, is coordinated by the purine N atoms of the 2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine ligands and two Cl atoms in a slightly distorted trans-square-planar coordination geometry [N—Pt—Cl angles = 89.91 (5) and 90.09 (5)°]. Weak intra­molecular N—H⋯Cl contacts occur. In the crystal, C—H⋯Cl and C—H⋯F contacts, as well as weak π–π stacking inter­actions [centroid–centroid distances = 3.5000 (11) and 3.6495 (12) Å] connect the mol­ecules into a three-dimensional architecture. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3684891/ /pubmed/23794993 http://dx.doi.org/10.1107/S1600536813013202 Text en © Trávníček and Štarha 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Trávníček, Zdeněk
Štarha, Pavel
trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)
title trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)
title_full trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)
title_fullStr trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)
title_full_unstemmed trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)
title_short trans-Dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9H-purine-κN (7)}platinum(II)
title_sort trans-dichloridobis{2-chloro-6-[(3-fluoro­benz­yl)amino]-9-isopropyl-9h-purine-κn (7)}platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684891/
https://www.ncbi.nlm.nih.gov/pubmed/23794993
http://dx.doi.org/10.1107/S1600536813013202
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AT starhapavel transdichloridobis2chloro63fluorobenzylamino9isopropyl9hpurinekn7platinumii

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