Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)

In the title mol­ecule, [Bi(C(6)H(5))(3)(C(4)H(5)O(2))(2)], the Bi(V) atom is in a distorted trigonal–bipyramidal environment with carboxyl­ate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) Å, but as a result of additional lo...

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Detalles Bibliográficos
Autores principales: Andreev, Pavel V., Somov, Nikolay V., Kalistratova, Olga S., Gushchin, Alexey V., Chuprunov, Evgeny V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684893/
https://www.ncbi.nlm.nih.gov/pubmed/23794995
http://dx.doi.org/10.1107/S1600536813013317
Descripción
Sumario:In the title mol­ecule, [Bi(C(6)H(5))(3)(C(4)H(5)O(2))(2)], the Bi(V) atom is in a distorted trigonal–bipyramidal environment with carboxyl­ate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) Å, but as a result of additional long Bi⋯O inter­actions [2.787 (3) and 2.734 (3) Å], one of the C—Bi—C angles is 148.62 (13)°. In the crystal, weak C—H⋯O hydrogen bonds connect pairs of mol­ecules into inversion dimers. These dimers are further connected by weak C—H⋯π inter­actions into chains along [100] .

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