Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)

In the title mol­ecule, [Bi(C(6)H(5))(3)(C(4)H(5)O(2))(2)], the Bi(V) atom is in a distorted trigonal–bipyramidal environment with carboxyl­ate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) Å, but as a result of additional lo...

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Autores principales: Andreev, Pavel V., Somov, Nikolay V., Kalistratova, Olga S., Gushchin, Alexey V., Chuprunov, Evgeny V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684893/
https://www.ncbi.nlm.nih.gov/pubmed/23794995
http://dx.doi.org/10.1107/S1600536813013317
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author Andreev, Pavel V.
Somov, Nikolay V.
Kalistratova, Olga S.
Gushchin, Alexey V.
Chuprunov, Evgeny V.
author_facet Andreev, Pavel V.
Somov, Nikolay V.
Kalistratova, Olga S.
Gushchin, Alexey V.
Chuprunov, Evgeny V.
author_sort Andreev, Pavel V.
collection PubMed
description In the title mol­ecule, [Bi(C(6)H(5))(3)(C(4)H(5)O(2))(2)], the Bi(V) atom is in a distorted trigonal–bipyramidal environment with carboxyl­ate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) Å, but as a result of additional long Bi⋯O inter­actions [2.787 (3) and 2.734 (3) Å], one of the C—Bi—C angles is 148.62 (13)°. In the crystal, weak C—H⋯O hydrogen bonds connect pairs of mol­ecules into inversion dimers. These dimers are further connected by weak C—H⋯π inter­actions into chains along [100] .
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spelling pubmed-36848932013-06-21 Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V) Andreev, Pavel V. Somov, Nikolay V. Kalistratova, Olga S. Gushchin, Alexey V. Chuprunov, Evgeny V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mol­ecule, [Bi(C(6)H(5))(3)(C(4)H(5)O(2))(2)], the Bi(V) atom is in a distorted trigonal–bipyramidal environment with carboxyl­ate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) Å, but as a result of additional long Bi⋯O inter­actions [2.787 (3) and 2.734 (3) Å], one of the C—Bi—C angles is 148.62 (13)°. In the crystal, weak C—H⋯O hydrogen bonds connect pairs of mol­ecules into inversion dimers. These dimers are further connected by weak C—H⋯π inter­actions into chains along [100] . International Union of Crystallography 2013-05-18 /pmc/articles/PMC3684893/ /pubmed/23794995 http://dx.doi.org/10.1107/S1600536813013317 Text en © Andreev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Andreev, Pavel V.
Somov, Nikolay V.
Kalistratova, Olga S.
Gushchin, Alexey V.
Chuprunov, Evgeny V.
Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)
title Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)
title_full Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)
title_fullStr Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)
title_full_unstemmed Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)
title_short Bis(but-2-enoato-κO)tri­phenyl­bis­muth(V)
title_sort bis(but-2-enoato-κo)tri­phenyl­bis­muth(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684893/
https://www.ncbi.nlm.nih.gov/pubmed/23794995
http://dx.doi.org/10.1107/S1600536813013317
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