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(Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate

The title compound, [Pt(C(6)H(6)O(4))(C(12)H(8)N(2))]·2H(2)O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclo­butane-1,1-di­carboxyl­ate dianion and two N atoms of the chelating 1,10-phenanthroline mol­...

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Detalles Bibliográficos
Autores principales: Štarha, Pavel, Trávníček, Zdeněk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684894/
https://www.ncbi.nlm.nih.gov/pubmed/23794996
http://dx.doi.org/10.1107/S1600536813013378
Descripción
Sumario:The title compound, [Pt(C(6)H(6)O(4))(C(12)H(8)N(2))]·2H(2)O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclo­butane-1,1-di­carboxyl­ate dianion and two N atoms of the chelating 1,10-phenanthroline mol­ecule (r.m.s. deviations of the PtO(2)N(2) units = 0.026 and 0.026 Å). Adjacent complex and water mol­ecules are connected through inter­molecular O—H⋯O hydrogen bonds and C—H⋯O, C⋯O [shortest C⋯O distance = 3.140 (5) Å], π–π [shortest C⋯C distances = 3.234 (6) and 3.347 (6) Å] and Pt⋯π [shortest Pt⋯C distance = 3.358 (4) Å] inter­actions into a three-dimensional network.