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(Cyclobutane-1,1-dicarboxylato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate
The title compound, [Pt(C(6)H(6)O(4))(C(12)H(8)N(2))]·2H(2)O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclobutane-1,1-dicarboxylate dianion and two N atoms of the chelating 1,10-phenanthroline mol...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684894/ https://www.ncbi.nlm.nih.gov/pubmed/23794996 http://dx.doi.org/10.1107/S1600536813013378 |
Sumario: | The title compound, [Pt(C(6)H(6)O(4))(C(12)H(8)N(2))]·2H(2)O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclobutane-1,1-dicarboxylate dianion and two N atoms of the chelating 1,10-phenanthroline molecule (r.m.s. deviations of the PtO(2)N(2) units = 0.026 and 0.026 Å). Adjacent complex and water molecules are connected through intermolecular O—H⋯O hydrogen bonds and C—H⋯O, C⋯O [shortest C⋯O distance = 3.140 (5) Å], π–π [shortest C⋯C distances = 3.234 (6) and 3.347 (6) Å] and Pt⋯π [shortest Pt⋯C distance = 3.358 (4) Å] interactions into a three-dimensional network. |
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