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(Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate

The title compound, [Pt(C(6)H(6)O(4))(C(12)H(8)N(2))]·2H(2)O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclo­butane-1,1-di­carboxyl­ate dianion and two N atoms of the chelating 1,10-phenanthroline mol­...

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Detalles Bibliográficos
Autores principales: Štarha, Pavel, Trávníček, Zdeněk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684894/
https://www.ncbi.nlm.nih.gov/pubmed/23794996
http://dx.doi.org/10.1107/S1600536813013378
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author Štarha, Pavel
Trávníček, Zdeněk
author_facet Štarha, Pavel
Trávníček, Zdeněk
author_sort Štarha, Pavel
collection PubMed
description The title compound, [Pt(C(6)H(6)O(4))(C(12)H(8)N(2))]·2H(2)O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclo­butane-1,1-di­carboxyl­ate dianion and two N atoms of the chelating 1,10-phenanthroline mol­ecule (r.m.s. deviations of the PtO(2)N(2) units = 0.026 and 0.026 Å). Adjacent complex and water mol­ecules are connected through inter­molecular O—H⋯O hydrogen bonds and C—H⋯O, C⋯O [shortest C⋯O distance = 3.140 (5) Å], π–π [shortest C⋯C distances = 3.234 (6) and 3.347 (6) Å] and Pt⋯π [shortest Pt⋯C distance = 3.358 (4) Å] inter­actions into a three-dimensional network.
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spelling pubmed-36848942013-06-21 (Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate Štarha, Pavel Trávníček, Zdeněk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pt(C(6)H(6)O(4))(C(12)H(8)N(2))]·2H(2)O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclo­butane-1,1-di­carboxyl­ate dianion and two N atoms of the chelating 1,10-phenanthroline mol­ecule (r.m.s. deviations of the PtO(2)N(2) units = 0.026 and 0.026 Å). Adjacent complex and water mol­ecules are connected through inter­molecular O—H⋯O hydrogen bonds and C—H⋯O, C⋯O [shortest C⋯O distance = 3.140 (5) Å], π–π [shortest C⋯C distances = 3.234 (6) and 3.347 (6) Å] and Pt⋯π [shortest Pt⋯C distance = 3.358 (4) Å] inter­actions into a three-dimensional network. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3684894/ /pubmed/23794996 http://dx.doi.org/10.1107/S1600536813013378 Text en © Štarha and Trávníček 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Štarha, Pavel
Trávníček, Zdeněk
(Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate
title (Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate
title_full (Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate
title_fullStr (Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate
title_full_unstemmed (Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate
title_short (Cyclo­butane-1,1-di­carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)platinum(II) dihydrate
title_sort (cyclo­butane-1,1-di­carboxyl­ato-κ(2) o,o′)(1,10-phenanthroline-κ(2) n,n′)platinum(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684894/
https://www.ncbi.nlm.nih.gov/pubmed/23794996
http://dx.doi.org/10.1107/S1600536813013378
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