(Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate

In the monomeric title complex, [Co(C(6)H(8)O(4))(C(10)H(9)N(3))(H(2)O)(2)]·3H(2)O, the distorted octa­hedral CoN(2)O(4) coordination environment comprises two N-atom donors from the bidentate di­pyridyldi­amine ligand, two O-atom donors from one of the carboxyl­ate groups of the bidentate chelating...

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Detalles Bibliográficos
Autores principales: Setifi, Zouaoui, Setifi, Fatima, Smith, Graham, El-Ghozzi, Malika, Rouag, Djamil-Azzeddine, Avignant, Daniel, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684895/
https://www.ncbi.nlm.nih.gov/pubmed/23794997
http://dx.doi.org/10.1107/S1600536813012981
Descripción
Sumario:In the monomeric title complex, [Co(C(6)H(8)O(4))(C(10)H(9)N(3))(H(2)O)(2)]·3H(2)O, the distorted octa­hedral CoN(2)O(4) coordination environment comprises two N-atom donors from the bidentate di­pyridyldi­amine ligand, two O-atom donors from one of the carboxyl­ate groups of the bidentate chelating adipate ligand and two water mol­ecules. In addition, there are three solvent water mol­ecules which are involved in both intra- and inter-unit O—H⋯O hydrogen-bonding inter­actions, which together with an amine–water N—H⋯O hydrogen bond produce a three-dimensional framework.

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