(Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate

In the monomeric title complex, [Co(C(6)H(8)O(4))(C(10)H(9)N(3))(H(2)O)(2)]·3H(2)O, the distorted octa­hedral CoN(2)O(4) coordination environment comprises two N-atom donors from the bidentate di­pyridyldi­amine ligand, two O-atom donors from one of the carboxyl­ate groups of the bidentate chelating...

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Autores principales: Setifi, Zouaoui, Setifi, Fatima, Smith, Graham, El-Ghozzi, Malika, Rouag, Djamil-Azzeddine, Avignant, Daniel, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684895/
https://www.ncbi.nlm.nih.gov/pubmed/23794997
http://dx.doi.org/10.1107/S1600536813012981
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author Setifi, Zouaoui
Setifi, Fatima
Smith, Graham
El-Ghozzi, Malika
Rouag, Djamil-Azzeddine
Avignant, Daniel
Merazig, Hocine
author_facet Setifi, Zouaoui
Setifi, Fatima
Smith, Graham
El-Ghozzi, Malika
Rouag, Djamil-Azzeddine
Avignant, Daniel
Merazig, Hocine
author_sort Setifi, Zouaoui
collection PubMed
description In the monomeric title complex, [Co(C(6)H(8)O(4))(C(10)H(9)N(3))(H(2)O)(2)]·3H(2)O, the distorted octa­hedral CoN(2)O(4) coordination environment comprises two N-atom donors from the bidentate di­pyridyldi­amine ligand, two O-atom donors from one of the carboxyl­ate groups of the bidentate chelating adipate ligand and two water mol­ecules. In addition, there are three solvent water mol­ecules which are involved in both intra- and inter-unit O—H⋯O hydrogen-bonding inter­actions, which together with an amine–water N—H⋯O hydrogen bond produce a three-dimensional framework.
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spelling pubmed-36848952013-06-21 (Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate Setifi, Zouaoui Setifi, Fatima Smith, Graham El-Ghozzi, Malika Rouag, Djamil-Azzeddine Avignant, Daniel Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [Co(C(6)H(8)O(4))(C(10)H(9)N(3))(H(2)O)(2)]·3H(2)O, the distorted octa­hedral CoN(2)O(4) coordination environment comprises two N-atom donors from the bidentate di­pyridyldi­amine ligand, two O-atom donors from one of the carboxyl­ate groups of the bidentate chelating adipate ligand and two water mol­ecules. In addition, there are three solvent water mol­ecules which are involved in both intra- and inter-unit O—H⋯O hydrogen-bonding inter­actions, which together with an amine–water N—H⋯O hydrogen bond produce a three-dimensional framework. International Union of Crystallography 2013-05-22 /pmc/articles/PMC3684895/ /pubmed/23794997 http://dx.doi.org/10.1107/S1600536813012981 Text en © Setifi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Setifi, Zouaoui
Setifi, Fatima
Smith, Graham
El-Ghozzi, Malika
Rouag, Djamil-Azzeddine
Avignant, Daniel
Merazig, Hocine
(Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate
title (Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate
title_full (Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate
title_fullStr (Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate
title_full_unstemmed (Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate
title_short (Adipato-κ(2) O,O′)di­aqua­[bis­(pyridin-2-yl-κN)amine]­cobalt(II) trihydrate
title_sort (adipato-κ(2) o,o′)di­aqua­[bis­(pyridin-2-yl-κn)amine]­cobalt(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684895/
https://www.ncbi.nlm.nih.gov/pubmed/23794997
http://dx.doi.org/10.1107/S1600536813012981
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