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Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate
The title compound, [Cu(4)(C(2)O(4))(2)(N(3))(4)(C(5)H(9)N(3))(2)]·0.9H(2)O, contains a tetranuclear Cu(II)-based molecule composed of two oxalate-bridged Cu(II) dimers linked through end-on azide ions and related by an inversion center. The tetranuclear unit contains two crystallographically indepe...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684896/ https://www.ncbi.nlm.nih.gov/pubmed/23794998 http://dx.doi.org/10.1107/S1600536813013329 |
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author | Liu, Chen Abboud, Khalil A. |
author_facet | Liu, Chen Abboud, Khalil A. |
author_sort | Liu, Chen |
collection | PubMed |
description | The title compound, [Cu(4)(C(2)O(4))(2)(N(3))(4)(C(5)H(9)N(3))(2)]·0.9H(2)O, contains a tetranuclear Cu(II)-based molecule composed of two oxalate-bridged Cu(II) dimers linked through end-on azide ions and related by an inversion center. The tetranuclear unit contains two crystallographically independent Cu(II) ions. One Cu(II) ion coordinates to two N atoms of a histamine molecule, two O atoms of a bridging oxalate ligand, and an N atom of an end-on bridging azide ligand, leading to an elongated square-pyramidal coordination geometry in which the azide ion occupies the axial position. The other Cu(II) ion, which has a square-planar coordination geometry, is coordinated by two O atoms of a bridging oxalate ligand and two N atoms of two different azide ligands, one which is bridging. In the crystal, a two-dimensional network parallel to (010) is formed by N—H⋯N and N—H⋯O hydrogen bonds. A partially occupied solvent water molecule refined to an occupancy of 0.447 (5). Two of the azide ligands were refined as disordered over two sets of sites with refined occupancies in the ratios 0.517 (8):0.483 (8) and 0.553 (5):0.447 (5). |
format | Online Article Text |
id | pubmed-3684896 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848962013-06-21 Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate Liu, Chen Abboud, Khalil A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(4)(C(2)O(4))(2)(N(3))(4)(C(5)H(9)N(3))(2)]·0.9H(2)O, contains a tetranuclear Cu(II)-based molecule composed of two oxalate-bridged Cu(II) dimers linked through end-on azide ions and related by an inversion center. The tetranuclear unit contains two crystallographically independent Cu(II) ions. One Cu(II) ion coordinates to two N atoms of a histamine molecule, two O atoms of a bridging oxalate ligand, and an N atom of an end-on bridging azide ligand, leading to an elongated square-pyramidal coordination geometry in which the azide ion occupies the axial position. The other Cu(II) ion, which has a square-planar coordination geometry, is coordinated by two O atoms of a bridging oxalate ligand and two N atoms of two different azide ligands, one which is bridging. In the crystal, a two-dimensional network parallel to (010) is formed by N—H⋯N and N—H⋯O hydrogen bonds. A partially occupied solvent water molecule refined to an occupancy of 0.447 (5). Two of the azide ligands were refined as disordered over two sets of sites with refined occupancies in the ratios 0.517 (8):0.483 (8) and 0.553 (5):0.447 (5). International Union of Crystallography 2013-05-22 /pmc/articles/PMC3684896/ /pubmed/23794998 http://dx.doi.org/10.1107/S1600536813013329 Text en © Liu and Abboud 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Chen Abboud, Khalil A. Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate |
title | Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate |
title_full | Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate |
title_fullStr | Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate |
title_full_unstemmed | Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate |
title_short | Di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(II) 0.9-hydrate |
title_sort | di-μ-azido-diazidodi-μ-oxalato-dihistaminetetracopper(ii) 0.9-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684896/ https://www.ncbi.nlm.nih.gov/pubmed/23794998 http://dx.doi.org/10.1107/S1600536813013329 |
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