Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate

The title compound, [Au(2)(C(27)H(26)P(2))(2)][NiCl(4)]·C(4)H(10)O, consists of a digold(I) complex cation, an [NiCl(4)](2−) complex anion and a diethyl ether solvent mol­ecule. Two 1,3-bis­(di­phenyl­phosphan­yl)propane (dppp) ligands bridge two Au(I) atoms, forming a metallacycle in which each of...

Descripción completa

Detalles Bibliográficos
Autores principales: Igashira-Kamiyama, Asako, Itai, Takuma, Arai, Yuka, Konno, Takumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684897/
https://www.ncbi.nlm.nih.gov/pubmed/23794999
http://dx.doi.org/10.1107/S1600536813013470
_version_ 1782273629015244800
author Igashira-Kamiyama, Asako
Itai, Takuma
Arai, Yuka
Konno, Takumi
author_facet Igashira-Kamiyama, Asako
Itai, Takuma
Arai, Yuka
Konno, Takumi
author_sort Igashira-Kamiyama, Asako
collection PubMed
description The title compound, [Au(2)(C(27)H(26)P(2))(2)][NiCl(4)]·C(4)H(10)O, consists of a digold(I) complex cation, an [NiCl(4)](2−) complex anion and a diethyl ether solvent mol­ecule. Two 1,3-bis­(di­phenyl­phosphan­yl)propane (dppp) ligands bridge two Au(I) atoms, forming a metallacycle in which each of the Au(I) atoms is coordinated in a slightly distorted linear environment by two P atoms. In the complex anion, the Ni(II) atom is coordinated by four chloride ligands in a distorted tetra­hedral geometry. The complex cation and the complex anion form a cation–anion pair through two Au⋯Cl contacts of 3.040 (1) and 3.021 (2) Å. One of the phenyl groups of the dppp ligand is disordered over two positions with equal occupancies.
format Online
Article
Text
id pubmed-3684897
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36848972013-06-21 Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate Igashira-Kamiyama, Asako Itai, Takuma Arai, Yuka Konno, Takumi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(2)(C(27)H(26)P(2))(2)][NiCl(4)]·C(4)H(10)O, consists of a digold(I) complex cation, an [NiCl(4)](2−) complex anion and a diethyl ether solvent mol­ecule. Two 1,3-bis­(di­phenyl­phosphan­yl)propane (dppp) ligands bridge two Au(I) atoms, forming a metallacycle in which each of the Au(I) atoms is coordinated in a slightly distorted linear environment by two P atoms. In the complex anion, the Ni(II) atom is coordinated by four chloride ligands in a distorted tetra­hedral geometry. The complex cation and the complex anion form a cation–anion pair through two Au⋯Cl contacts of 3.040 (1) and 3.021 (2) Å. One of the phenyl groups of the dppp ligand is disordered over two positions with equal occupancies. International Union of Crystallography 2013-05-22 /pmc/articles/PMC3684897/ /pubmed/23794999 http://dx.doi.org/10.1107/S1600536813013470 Text en © Igashira-Kamiyama et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Igashira-Kamiyama, Asako
Itai, Takuma
Arai, Yuka
Konno, Takumi
Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate
title Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate
title_full Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate
title_fullStr Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate
title_full_unstemmed Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate
title_short Bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) P:P′]digold(I) tetra­chloridonickelate(II) diethyl ether monosolvate
title_sort bis[μ-1,3-bis­(di­phenyl­phosphan­yl)propane-κ(2) p:p′]digold(i) tetra­chloridonickelate(ii) diethyl ether monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684897/
https://www.ncbi.nlm.nih.gov/pubmed/23794999
http://dx.doi.org/10.1107/S1600536813013470
work_keys_str_mv AT igashirakamiyamaasako bism13bisdiphenylphosphanylpropanek2ppdigolditetrachloridonickelateiidiethylethermonosolvate
AT itaitakuma bism13bisdiphenylphosphanylpropanek2ppdigolditetrachloridonickelateiidiethylethermonosolvate
AT araiyuka bism13bisdiphenylphosphanylpropanek2ppdigolditetrachloridonickelateiidiethylethermonosolvate
AT konnotakumi bism13bisdiphenylphosphanylpropanek2ppdigolditetrachloridonickelateiidiethylethermonosolvate

Ejemplares similares