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Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate

The structure of the title complex, [FeRu(C(5)H(5))(C(5)H(4)OPS(2))(CO)(C(18)H(15)P)(2)(H(2)O)]·CH(2)Cl(2), consists of one neutral [{FcP(O)S(2)}Ru(CO)(H(2)O)(PPh(3))(2)] complex [Fc = Fe(η(5)-C(5)H(4))(η(5)-C(5)H(5))] and one CH(2)Cl(2) solvent mol­ecule. The geometry around the Ru(II) atom is pseu...

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Detalles Bibliográficos
Autores principales: Zhu, Hang, Ma, Qing, Shi, Hua-Tian, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684901/
https://www.ncbi.nlm.nih.gov/pubmed/23795003
http://dx.doi.org/10.1107/S1600536813014311
Descripción
Sumario:The structure of the title complex, [FeRu(C(5)H(5))(C(5)H(4)OPS(2))(CO)(C(18)H(15)P)(2)(H(2)O)]·CH(2)Cl(2), consists of one neutral [{FcP(O)S(2)}Ru(CO)(H(2)O)(PPh(3))(2)] complex [Fc = Fe(η(5)-C(5)H(4))(η(5)-C(5)H(5))] and one CH(2)Cl(2) solvent mol­ecule. The geometry around the Ru(II) atom is pseudo-octa­hedral, with two cis-binding PPh(3) ligands and one chelating bidentate [Fc(O)PS(2)](2−) ligand via two S atoms. The average Ru—S and Ru—P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru—O and Ru—C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O—H⋯O hydrogen bonds link adjacent mol­ecules into dimers.