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Aquacarbonyl(ferrocenyldithiophosphonato-κ(2) S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate
The structure of the title complex, [FeRu(C(5)H(5))(C(5)H(4)OPS(2))(CO)(C(18)H(15)P)(2)(H(2)O)]·CH(2)Cl(2), consists of one neutral [{FcP(O)S(2)}Ru(CO)(H(2)O)(PPh(3))(2)] complex [Fc = Fe(η(5)-C(5)H(4))(η(5)-C(5)H(5))] and one CH(2)Cl(2) solvent molecule. The geometry around the Ru(II) atom is pseu...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684901/ https://www.ncbi.nlm.nih.gov/pubmed/23795003 http://dx.doi.org/10.1107/S1600536813014311 |
Sumario: | The structure of the title complex, [FeRu(C(5)H(5))(C(5)H(4)OPS(2))(CO)(C(18)H(15)P)(2)(H(2)O)]·CH(2)Cl(2), consists of one neutral [{FcP(O)S(2)}Ru(CO)(H(2)O)(PPh(3))(2)] complex [Fc = Fe(η(5)-C(5)H(4))(η(5)-C(5)H(5))] and one CH(2)Cl(2) solvent molecule. The geometry around the Ru(II) atom is pseudo-octahedral, with two cis-binding PPh(3) ligands and one chelating bidentate [Fc(O)PS(2)](2−) ligand via two S atoms. The average Ru—S and Ru—P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru—O and Ru—C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O—H⋯O hydrogen bonds link adjacent molecules into dimers. |
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