Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate

The structure of the title complex, [FeRu(C(5)H(5))(C(5)H(4)OPS(2))(CO)(C(18)H(15)P)(2)(H(2)O)]·CH(2)Cl(2), consists of one neutral [{FcP(O)S(2)}Ru(CO)(H(2)O)(PPh(3))(2)] complex [Fc = Fe(η(5)-C(5)H(4))(η(5)-C(5)H(5))] and one CH(2)Cl(2) solvent mol­ecule. The geometry around the Ru(II) atom is pseu...

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Autores principales: Zhu, Hang, Ma, Qing, Shi, Hua-Tian, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684901/
https://www.ncbi.nlm.nih.gov/pubmed/23795003
http://dx.doi.org/10.1107/S1600536813014311
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author Zhu, Hang
Ma, Qing
Shi, Hua-Tian
Chen, Qun
Zhang, Qian-Feng
author_facet Zhu, Hang
Ma, Qing
Shi, Hua-Tian
Chen, Qun
Zhang, Qian-Feng
author_sort Zhu, Hang
collection PubMed
description The structure of the title complex, [FeRu(C(5)H(5))(C(5)H(4)OPS(2))(CO)(C(18)H(15)P)(2)(H(2)O)]·CH(2)Cl(2), consists of one neutral [{FcP(O)S(2)}Ru(CO)(H(2)O)(PPh(3))(2)] complex [Fc = Fe(η(5)-C(5)H(4))(η(5)-C(5)H(5))] and one CH(2)Cl(2) solvent mol­ecule. The geometry around the Ru(II) atom is pseudo-octa­hedral, with two cis-binding PPh(3) ligands and one chelating bidentate [Fc(O)PS(2)](2−) ligand via two S atoms. The average Ru—S and Ru—P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru—O and Ru—C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O—H⋯O hydrogen bonds link adjacent mol­ecules into dimers.
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spelling pubmed-36849012013-06-21 Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate Zhu, Hang Ma, Qing Shi, Hua-Tian Chen, Qun Zhang, Qian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title complex, [FeRu(C(5)H(5))(C(5)H(4)OPS(2))(CO)(C(18)H(15)P)(2)(H(2)O)]·CH(2)Cl(2), consists of one neutral [{FcP(O)S(2)}Ru(CO)(H(2)O)(PPh(3))(2)] complex [Fc = Fe(η(5)-C(5)H(4))(η(5)-C(5)H(5))] and one CH(2)Cl(2) solvent mol­ecule. The geometry around the Ru(II) atom is pseudo-octa­hedral, with two cis-binding PPh(3) ligands and one chelating bidentate [Fc(O)PS(2)](2−) ligand via two S atoms. The average Ru—S and Ru—P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru—O and Ru—C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O—H⋯O hydrogen bonds link adjacent mol­ecules into dimers. International Union of Crystallography 2013-05-31 /pmc/articles/PMC3684901/ /pubmed/23795003 http://dx.doi.org/10.1107/S1600536813014311 Text en © Zhu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Hang
Ma, Qing
Shi, Hua-Tian
Chen, Qun
Zhang, Qian-Feng
Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate
title Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate
title_full Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate
title_fullStr Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate
title_full_unstemmed Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate
title_short Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) dichloromethane mono­solvate
title_sort aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-κ(2) s,s′)bis­(tri­phenyl­phosphane-κp)ruthenium(ii) dichloromethane mono­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684901/
https://www.ncbi.nlm.nih.gov/pubmed/23795003
http://dx.doi.org/10.1107/S1600536813014311
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