Tetra­ethyl­ammonium trichlorido(N,N′-di­methyl­formamide-κO)zinc

The title complex salt, (C(8)H(20)N)[ZnCl(3)(C(3)H(7)NO)], contains one [Et(4)N](+) cation (Et is ethyl) and one [ZnCl(3)(DMF)](−) anion (DMF is di­methyl­formamide). In the anion, the zinc atom is tetra­hedrally coordinated by a DMF ligand via the O atom and by three terminal Cl atoms. The average...

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Detalles Bibliográficos
Autores principales: Chao, Guo-Ping, Shi, Hua-Tian, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684902/
https://www.ncbi.nlm.nih.gov/pubmed/23795004
http://dx.doi.org/10.1107/S1600536813014323
Descripción
Sumario:The title complex salt, (C(8)H(20)N)[ZnCl(3)(C(3)H(7)NO)], contains one [Et(4)N](+) cation (Et is ethyl) and one [ZnCl(3)(DMF)](−) anion (DMF is di­methyl­formamide). In the anion, the zinc atom is tetra­hedrally coordinated by a DMF ligand via the O atom and by three terminal Cl atoms. The average Zn—Cl bond length and Cl—Zn—Cl angle are 2.243 (11) Å and 114 (3)°, respectively.

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