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Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN (1))cobalt(II)
In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) atom is located on an inversion center and is coordinated by two 3-chlorobenzoate (CB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly disto...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684906/ https://www.ncbi.nlm.nih.gov/pubmed/23795008 http://dx.doi.org/10.1107/S160053681301458X |
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author | Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Bozkurt, Nihat |
collection | PubMed |
description | In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) atom is located on an inversion center and is coordinated by two 3-chlorobenzoate (CB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the molecules into a two-dimensional network lying parallel to (101). π–π stacking between parallel pyridine rings of adjacent molecules [centroid–centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure. |
format | Online Article Text |
id | pubmed-3684906 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36849062013-06-21 Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN (1))cobalt(II) Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) atom is located on an inversion center and is coordinated by two 3-chlorobenzoate (CB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the molecules into a two-dimensional network lying parallel to (101). π–π stacking between parallel pyridine rings of adjacent molecules [centroid–centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure. International Union of Crystallography 2013-05-31 /pmc/articles/PMC3684906/ /pubmed/23795008 http://dx.doi.org/10.1107/S160053681301458X Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN (1))cobalt(II) |
title | Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN
(1))cobalt(II) |
title_full | Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN
(1))cobalt(II) |
title_fullStr | Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN
(1))cobalt(II) |
title_full_unstemmed | Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN
(1))cobalt(II) |
title_short | Diaquabis(3-chlorobenzoato-κO)bis(nicotinamide-κN
(1))cobalt(II) |
title_sort | diaquabis(3-chlorobenzoato-κo)bis(nicotinamide-κn
(1))cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684906/ https://www.ncbi.nlm.nih.gov/pubmed/23795008 http://dx.doi.org/10.1107/S160053681301458X |
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