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Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)

In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) atom is located on an inversion center and is coordinated by two 3-chloro­benzoate (CB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane form a slightly disto...

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Autores principales: Bozkurt, Nihat, Dilek, Nefise, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684906/
https://www.ncbi.nlm.nih.gov/pubmed/23795008
http://dx.doi.org/10.1107/S160053681301458X
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author Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Bozkurt, Nihat
collection PubMed
description In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) atom is located on an inversion center and is coordinated by two 3-chloro­benzoate (CB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network lying parallel to (101). π–π stacking between parallel pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure.
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spelling pubmed-36849062013-06-21 Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II) Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) atom is located on an inversion center and is coordinated by two 3-chloro­benzoate (CB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network lying parallel to (101). π–π stacking between parallel pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure. International Union of Crystallography 2013-05-31 /pmc/articles/PMC3684906/ /pubmed/23795008 http://dx.doi.org/10.1107/S160053681301458X Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_fullStr Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full_unstemmed Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_short Di­aqua­bis­(3-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_sort di­aqua­bis­(3-chloro­benzoato-κo)bis­(nicotinamide-κn (1))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684906/
https://www.ncbi.nlm.nih.gov/pubmed/23795008
http://dx.doi.org/10.1107/S160053681301458X
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