Cargando…

Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate

In the title compound, C(22)H(20)ClN(3)O(4), the central pyrrolidine ring adopts an envelope conformation on the N atom. The indolinone systems are individually roughly planar, with maximum deviations from their mean planes of 0.130 Å for the spiro C atom of the indolinone unit and 0.172 Å for the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Kannan, Piskala Subburaman, Yuvaraj, PanneerSelvam, Manivannan, Karthikeyan, Reddy, Boreddy Siva Rami, SubbiahPandi, Arunachalathevar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684914/
https://www.ncbi.nlm.nih.gov/pubmed/23795016
http://dx.doi.org/10.1107/S1600536813011501
_version_ 1782273632853032960
author Kannan, Piskala Subburaman
Yuvaraj, PanneerSelvam
Manivannan, Karthikeyan
Reddy, Boreddy Siva Rami
SubbiahPandi, Arunachalathevar
author_facet Kannan, Piskala Subburaman
Yuvaraj, PanneerSelvam
Manivannan, Karthikeyan
Reddy, Boreddy Siva Rami
SubbiahPandi, Arunachalathevar
author_sort Kannan, Piskala Subburaman
collection PubMed
description In the title compound, C(22)H(20)ClN(3)O(4), the central pyrrolidine ring adopts an envelope conformation on the N atom. The indolinone systems are individually roughly planar, with maximum deviations from their mean planes of 0.130 Å for the spiro C atom of the indolinone unit and 0.172 Å for the carbonyl C atom of the 5-chloro-1-methyl­indolinone unit. They make dihedral angles of 77.7 (8) and 86.1 (8)° with the mean plane through the central pyrrolidine ring. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds supported by C—H⋯O contacts into chains along the ab diagonal. The structure also features C—H⋯O hydrogen bonds, forming R (2) (2)(8) and R (2) (2)(16) rings and generating a three-dimensional array.
format Online
Article
Text
id pubmed-3684914
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36849142013-06-21 Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate Kannan, Piskala Subburaman Yuvaraj, PanneerSelvam Manivannan, Karthikeyan Reddy, Boreddy Siva Rami SubbiahPandi, Arunachalathevar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(20)ClN(3)O(4), the central pyrrolidine ring adopts an envelope conformation on the N atom. The indolinone systems are individually roughly planar, with maximum deviations from their mean planes of 0.130 Å for the spiro C atom of the indolinone unit and 0.172 Å for the carbonyl C atom of the 5-chloro-1-methyl­indolinone unit. They make dihedral angles of 77.7 (8) and 86.1 (8)° with the mean plane through the central pyrrolidine ring. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds supported by C—H⋯O contacts into chains along the ab diagonal. The structure also features C—H⋯O hydrogen bonds, forming R (2) (2)(8) and R (2) (2)(16) rings and generating a three-dimensional array. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684914/ /pubmed/23795016 http://dx.doi.org/10.1107/S1600536813011501 Text en © Kannan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kannan, Piskala Subburaman
Yuvaraj, PanneerSelvam
Manivannan, Karthikeyan
Reddy, Boreddy Siva Rami
SubbiahPandi, Arunachalathevar
Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate
title Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate
title_full Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate
title_fullStr Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate
title_full_unstemmed Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate
title_short Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate
title_sort methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodi­spiro­[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684914/
https://www.ncbi.nlm.nih.gov/pubmed/23795016
http://dx.doi.org/10.1107/S1600536813011501
work_keys_str_mv AT kannanpiskalasubburaman methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate
AT yuvarajpanneerselvam methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate
AT manivannankarthikeyan methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate
AT reddyboreddysivarami methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate
AT subbiahpandiarunachalathevar methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate