Cargando…
Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate
In the title compound, C(22)H(20)ClN(3)O(4), the central pyrrolidine ring adopts an envelope conformation on the N atom. The indolinone systems are individually roughly planar, with maximum deviations from their mean planes of 0.130 Å for the spiro C atom of the indolinone unit and 0.172 Å for the c...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684914/ https://www.ncbi.nlm.nih.gov/pubmed/23795016 http://dx.doi.org/10.1107/S1600536813011501 |
_version_ | 1782273632853032960 |
---|---|
author | Kannan, Piskala Subburaman Yuvaraj, PanneerSelvam Manivannan, Karthikeyan Reddy, Boreddy Siva Rami SubbiahPandi, Arunachalathevar |
author_facet | Kannan, Piskala Subburaman Yuvaraj, PanneerSelvam Manivannan, Karthikeyan Reddy, Boreddy Siva Rami SubbiahPandi, Arunachalathevar |
author_sort | Kannan, Piskala Subburaman |
collection | PubMed |
description | In the title compound, C(22)H(20)ClN(3)O(4), the central pyrrolidine ring adopts an envelope conformation on the N atom. The indolinone systems are individually roughly planar, with maximum deviations from their mean planes of 0.130 Å for the spiro C atom of the indolinone unit and 0.172 Å for the carbonyl C atom of the 5-chloro-1-methylindolinone unit. They make dihedral angles of 77.7 (8) and 86.1 (8)° with the mean plane through the central pyrrolidine ring. In the crystal, molecules are linked by N—H⋯O hydrogen bonds supported by C—H⋯O contacts into chains along the ab diagonal. The structure also features C—H⋯O hydrogen bonds, forming R (2) (2)(8) and R (2) (2)(16) rings and generating a three-dimensional array. |
format | Online Article Text |
id | pubmed-3684914 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36849142013-06-21 Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate Kannan, Piskala Subburaman Yuvaraj, PanneerSelvam Manivannan, Karthikeyan Reddy, Boreddy Siva Rami SubbiahPandi, Arunachalathevar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(20)ClN(3)O(4), the central pyrrolidine ring adopts an envelope conformation on the N atom. The indolinone systems are individually roughly planar, with maximum deviations from their mean planes of 0.130 Å for the spiro C atom of the indolinone unit and 0.172 Å for the carbonyl C atom of the 5-chloro-1-methylindolinone unit. They make dihedral angles of 77.7 (8) and 86.1 (8)° with the mean plane through the central pyrrolidine ring. In the crystal, molecules are linked by N—H⋯O hydrogen bonds supported by C—H⋯O contacts into chains along the ab diagonal. The structure also features C—H⋯O hydrogen bonds, forming R (2) (2)(8) and R (2) (2)(16) rings and generating a three-dimensional array. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684914/ /pubmed/23795016 http://dx.doi.org/10.1107/S1600536813011501 Text en © Kannan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kannan, Piskala Subburaman Yuvaraj, PanneerSelvam Manivannan, Karthikeyan Reddy, Boreddy Siva Rami SubbiahPandi, Arunachalathevar Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate |
title | Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate |
title_full | Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate |
title_fullStr | Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate |
title_full_unstemmed | Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate |
title_short | Methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate |
title_sort | methyl 5′′-chloro-1′,1′′-dimethyl-2,2′′-dioxodispiro[indoline-3,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684914/ https://www.ncbi.nlm.nih.gov/pubmed/23795016 http://dx.doi.org/10.1107/S1600536813011501 |
work_keys_str_mv | AT kannanpiskalasubburaman methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate AT yuvarajpanneerselvam methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate AT manivannankarthikeyan methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate AT reddyboreddysivarami methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate AT subbiahpandiarunachalathevar methyl5chloro11dimethyl22dioxodispiroindoline32pyrrolidine33indoline4carboxylate |