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10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile

In the title mol­ecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respective...

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Detalles Bibliográficos
Autores principales: Thiruvalluvar, A., Yamuna, E., Archana, R., Rajendra Prasad, K. J., Butcher, R. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684919/
https://www.ncbi.nlm.nih.gov/pubmed/23795021
http://dx.doi.org/10.1107/S1600536813011823
Descripción
Sumario:In the title mol­ecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds generate R (2) (2)(14) loops and a C—H⋯N inter­action is also found. Mol­ecules are further linked by a number of π–π interactions [centroid–centroid distances vary from 3.5702 (5) to 3.7068 (6) Å], forming a three-dimensional network.