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10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile
In the title molecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respective...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684919/ https://www.ncbi.nlm.nih.gov/pubmed/23795021 http://dx.doi.org/10.1107/S1600536813011823 |
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author | Thiruvalluvar, A. Yamuna, E. Archana, R. Rajendra Prasad, K. J. Butcher, R. J. |
author_facet | Thiruvalluvar, A. Yamuna, E. Archana, R. Rajendra Prasad, K. J. Butcher, R. J. |
author_sort | Thiruvalluvar, A. |
collection | PubMed |
description | In the title molecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds generate R (2) (2)(14) loops and a C—H⋯N interaction is also found. Molecules are further linked by a number of π–π interactions [centroid–centroid distances vary from 3.5702 (5) to 3.7068 (6) Å], forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-3684919 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36849192013-06-21 10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile Thiruvalluvar, A. Yamuna, E. Archana, R. Rajendra Prasad, K. J. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds generate R (2) (2)(14) loops and a C—H⋯N interaction is also found. Molecules are further linked by a number of π–π interactions [centroid–centroid distances vary from 3.5702 (5) to 3.7068 (6) Å], forming a three-dimensional network. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684919/ /pubmed/23795021 http://dx.doi.org/10.1107/S1600536813011823 Text en © Thiruvalluvar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Thiruvalluvar, A. Yamuna, E. Archana, R. Rajendra Prasad, K. J. Butcher, R. J. 10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile |
title | 10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile |
title_full | 10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile |
title_fullStr | 10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile |
title_full_unstemmed | 10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile |
title_short | 10-Methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile |
title_sort | 10-methyl-2-oxo-4-phenyl-2,11-dihydropyrano[2,3-a]carbazole-3-carbonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684919/ https://www.ncbi.nlm.nih.gov/pubmed/23795021 http://dx.doi.org/10.1107/S1600536813011823 |
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