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10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile

In the title mol­ecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respective...

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Autores principales: Thiruvalluvar, A., Yamuna, E., Archana, R., Rajendra Prasad, K. J., Butcher, R. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684919/
https://www.ncbi.nlm.nih.gov/pubmed/23795021
http://dx.doi.org/10.1107/S1600536813011823
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author Thiruvalluvar, A.
Yamuna, E.
Archana, R.
Rajendra Prasad, K. J.
Butcher, R. J.
author_facet Thiruvalluvar, A.
Yamuna, E.
Archana, R.
Rajendra Prasad, K. J.
Butcher, R. J.
author_sort Thiruvalluvar, A.
collection PubMed
description In the title mol­ecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds generate R (2) (2)(14) loops and a C—H⋯N inter­action is also found. Mol­ecules are further linked by a number of π–π interactions [centroid–centroid distances vary from 3.5702 (5) to 3.7068 (6) Å], forming a three-dimensional network.
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spelling pubmed-36849192013-06-21 10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile Thiruvalluvar, A. Yamuna, E. Archana, R. Rajendra Prasad, K. J. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(23)H(14)N(2)O(2), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1018 (8) Å]. The pyrrole ring makes dihedral angles of 4.44 (5), 3.84 (5), 2.18 (5) and 56.44 (5)° with the pyran, fused benzene rings and phenyl ring, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds generate R (2) (2)(14) loops and a C—H⋯N inter­action is also found. Mol­ecules are further linked by a number of π–π interactions [centroid–centroid distances vary from 3.5702 (5) to 3.7068 (6) Å], forming a three-dimensional network. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684919/ /pubmed/23795021 http://dx.doi.org/10.1107/S1600536813011823 Text en © Thiruvalluvar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thiruvalluvar, A.
Yamuna, E.
Archana, R.
Rajendra Prasad, K. J.
Butcher, R. J.
10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile
title 10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile
title_full 10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile
title_fullStr 10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile
title_full_unstemmed 10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile
title_short 10-Methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile
title_sort 10-methyl-2-oxo-4-phenyl-2,11-di­hydro­pyrano[2,3-a]carbazole-3-carbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684919/
https://www.ncbi.nlm.nih.gov/pubmed/23795021
http://dx.doi.org/10.1107/S1600536813011823
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