3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate

In the title compound, C(5)H(9)N(4) (+)·NO(3) (−), the organic cations and the nitrate anions have both crystallographically imposed mirror symmetry and are linked via N—H⋯O hydrogen bonds, forming infinite chains running along the c-axis direction. The values of the N—O bond lengths [1.2256 (19)–1....

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Autores principales: Bel Haj Salah, Souhir, Mrad, Mohamed Lahbib, Ferretti, Valeria, Lefebvre, Frederic, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684929/
https://www.ncbi.nlm.nih.gov/pubmed/23795031
http://dx.doi.org/10.1107/S1600536813012026
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author Bel Haj Salah, Souhir
Mrad, Mohamed Lahbib
Ferretti, Valeria
Lefebvre, Frederic
Ben Nasr, Cherif
author_facet Bel Haj Salah, Souhir
Mrad, Mohamed Lahbib
Ferretti, Valeria
Lefebvre, Frederic
Ben Nasr, Cherif
author_sort Bel Haj Salah, Souhir
collection PubMed
description In the title compound, C(5)H(9)N(4) (+)·NO(3) (−), the organic cations and the nitrate anions have both crystallographically imposed mirror symmetry and are linked via N—H⋯O hydrogen bonds, forming infinite chains running along the c-axis direction. The values of the N—O bond lengths [1.2256 (19)–1.2642 (18) Å] and O—N—O angles [118.39 (16)–121.64 (15)°] indicate that the nitrate anion exhibits a slightly distorted C(3h) geometry. The N atom of the NH(2) group has sp (2) character.
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spelling pubmed-36849292013-06-21 3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate Bel Haj Salah, Souhir Mrad, Mohamed Lahbib Ferretti, Valeria Lefebvre, Frederic Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(9)N(4) (+)·NO(3) (−), the organic cations and the nitrate anions have both crystallographically imposed mirror symmetry and are linked via N—H⋯O hydrogen bonds, forming infinite chains running along the c-axis direction. The values of the N—O bond lengths [1.2256 (19)–1.2642 (18) Å] and O—N—O angles [118.39 (16)–121.64 (15)°] indicate that the nitrate anion exhibits a slightly distorted C(3h) geometry. The N atom of the NH(2) group has sp (2) character. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3684929/ /pubmed/23795031 http://dx.doi.org/10.1107/S1600536813012026 Text en © Bel Haj Salah et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bel Haj Salah, Souhir
Mrad, Mohamed Lahbib
Ferretti, Valeria
Lefebvre, Frederic
Ben Nasr, Cherif
3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate
title 3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate
title_full 3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate
title_fullStr 3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate
title_full_unstemmed 3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate
title_short 3-Amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate
title_sort 3-amino-5,6-dimethyl-1,2,4-triazin-2-ium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684929/
https://www.ncbi.nlm.nih.gov/pubmed/23795031
http://dx.doi.org/10.1107/S1600536813012026
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