3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one

In the title compound, C(24)H(25)N(3)O(2)S(2), the piperidine ring adopts a distorted boat conformation. The phenyl rings subtend angles of 75.6 (1)° and 86.3 (1)° with the mean plane of the piperidine ring. In the crystal, mol­ecules are linked through a network C—H⋯N hydrogen bonds, forming zigzag...

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Detalles Bibliográficos
Autores principales: Ganesan, S., Sugumar, P., Ananthan, S., Ponnuswamy, M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684930/
https://www.ncbi.nlm.nih.gov/pubmed/23795032
http://dx.doi.org/10.1107/S1600536813012014
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author Ganesan, S.
Sugumar, P.
Ananthan, S.
Ponnuswamy, M. N.
author_facet Ganesan, S.
Sugumar, P.
Ananthan, S.
Ponnuswamy, M. N.
author_sort Ganesan, S.
collection PubMed
description In the title compound, C(24)H(25)N(3)O(2)S(2), the piperidine ring adopts a distorted boat conformation. The phenyl rings subtend angles of 75.6 (1)° and 86.3 (1)° with the mean plane of the piperidine ring. In the crystal, mol­ecules are linked through a network C—H⋯N hydrogen bonds, forming zigzag chains along [100]. The thia­diazol ring methyl group is disordered over two positions with an occupancy ratio of 0.69 (4):0.31 (4).
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spelling pubmed-36849302013-06-21 3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one Ganesan, S. Sugumar, P. Ananthan, S. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(25)N(3)O(2)S(2), the piperidine ring adopts a distorted boat conformation. The phenyl rings subtend angles of 75.6 (1)° and 86.3 (1)° with the mean plane of the piperidine ring. In the crystal, mol­ecules are linked through a network C—H⋯N hydrogen bonds, forming zigzag chains along [100]. The thia­diazol ring methyl group is disordered over two positions with an occupancy ratio of 0.69 (4):0.31 (4). International Union of Crystallography 2013-05-11 /pmc/articles/PMC3684930/ /pubmed/23795032 http://dx.doi.org/10.1107/S1600536813012014 Text en © Ganesan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ganesan, S.
Sugumar, P.
Ananthan, S.
Ponnuswamy, M. N.
3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one
title 3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one
title_full 3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one
title_fullStr 3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one
title_full_unstemmed 3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one
title_short 3,5-Dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one
title_sort 3,5-dimethyl-1-{2-[(5-methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]acet­yl}-2,6-diphenylpiperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684930/
https://www.ncbi.nlm.nih.gov/pubmed/23795032
http://dx.doi.org/10.1107/S1600536813012014
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AT ananthans 35dimethyl125methyl134thiadiazol2ylsulfanylacetyl26diphenylpiperidin4one
AT ponnuswamymn 35dimethyl125methyl134thiadiazol2ylsulfanylacetyl26diphenylpiperidin4one

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