Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate

The title compound, C(12)H(10)ClNO(3), the indoline ring system is essentially planar, with a maximum deviation of 0.009 Å for the N atom. The indoline ring and acetate group are essentially coplanar, with a maximum deviation of 0.086 Å for the O atom. The mean plane through the methoxy­carbonyl­met...

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Autores principales: Kannan, Piskala Subburaman, Yuvaraj, PanneerSelvam, Manivannan, Karthikeyan, Reddy, Boreddy S. R., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684938/
https://www.ncbi.nlm.nih.gov/pubmed/23795040
http://dx.doi.org/10.1107/S1600536813011768
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author Kannan, Piskala Subburaman
Yuvaraj, PanneerSelvam
Manivannan, Karthikeyan
Reddy, Boreddy S. R.
SubbiahPandi, A.
author_facet Kannan, Piskala Subburaman
Yuvaraj, PanneerSelvam
Manivannan, Karthikeyan
Reddy, Boreddy S. R.
SubbiahPandi, A.
author_sort Kannan, Piskala Subburaman
collection PubMed
description The title compound, C(12)H(10)ClNO(3), the indoline ring system is essentially planar, with a maximum deviation of 0.009 Å for the N atom. The indoline ring and acetate group are essentially coplanar, with a maximum deviation of 0.086 Å for the O atom. The mean plane through the methoxy­carbonyl­methyl group forms a dihedral angle of 3.68 (5)° with the plane of the indoline ring system. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen-bond inter­action. In the crystal, π–π stacking inter­actions [centroid–centroid distance = 3.7677 (8) Å] occur between benzene rings, forming a chain running along the c-axis direction.
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spelling pubmed-36849382013-06-21 Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate Kannan, Piskala Subburaman Yuvaraj, PanneerSelvam Manivannan, Karthikeyan Reddy, Boreddy S. R. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(10)ClNO(3), the indoline ring system is essentially planar, with a maximum deviation of 0.009 Å for the N atom. The indoline ring and acetate group are essentially coplanar, with a maximum deviation of 0.086 Å for the O atom. The mean plane through the methoxy­carbonyl­methyl group forms a dihedral angle of 3.68 (5)° with the plane of the indoline ring system. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen-bond inter­action. In the crystal, π–π stacking inter­actions [centroid–centroid distance = 3.7677 (8) Å] occur between benzene rings, forming a chain running along the c-axis direction. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3684938/ /pubmed/23795040 http://dx.doi.org/10.1107/S1600536813011768 Text en © Kannan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kannan, Piskala Subburaman
Yuvaraj, PanneerSelvam
Manivannan, Karthikeyan
Reddy, Boreddy S. R.
SubbiahPandi, A.
Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate
title Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate
title_full Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate
title_fullStr Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate
title_full_unstemmed Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate
title_short Methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1H-indol-3-ylidene)acetate
title_sort methyl 2-(5-chloro-1-methyl-2-oxo-2,3-di­hydro-1h-indol-3-ylidene)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684938/
https://www.ncbi.nlm.nih.gov/pubmed/23795040
http://dx.doi.org/10.1107/S1600536813011768
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AT manivannankarthikeyan methyl25chloro1methyl2oxo23dihydro1hindol3ylideneacetate
AT reddyboreddysr methyl25chloro1methyl2oxo23dihydro1hindol3ylideneacetate
AT subbiahpandia methyl25chloro1methyl2oxo23dihydro1hindol3ylideneacetate

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