4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]

The title compound, C(17)H(14)Cl(4)N(5)OP(3), is a spiro-phosphazene derivative with bulky naphthalene and pyridine rings. The phosphazene and the six-membered N/O rings are in flattened-boat and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented...

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Autores principales: Işıklan, Muhammet, Sonkaya, Ömer, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685025/
https://www.ncbi.nlm.nih.gov/pubmed/23795044
http://dx.doi.org/10.1107/S1600536813012348
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author Işıklan, Muhammet
Sonkaya, Ömer
Hökelek, Tuncer
author_facet Işıklan, Muhammet
Sonkaya, Ömer
Hökelek, Tuncer
author_sort Işıklan, Muhammet
collection PubMed
description The title compound, C(17)H(14)Cl(4)N(5)OP(3), is a spiro-phosphazene derivative with bulky naphthalene and pyridine rings. The phosphazene and the six-membered N/O rings are in flattened-boat and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented at a dihedral angle of 18.06 (8)°. In the crystal, weak π–π stacking between the pyridine rings and between the pyridine rings and the naphthalene ring system [centroid–centroid distances = 3.594 (2) and 3.961 (2) Å, respectively] occur. Weak C—H⋯π inter­actions are also observed. These interactions link the molecules into a three-dimensional supramolecular network.
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spelling pubmed-36850252013-06-21 4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine] Işıklan, Muhammet Sonkaya, Ömer Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(14)Cl(4)N(5)OP(3), is a spiro-phosphazene derivative with bulky naphthalene and pyridine rings. The phosphazene and the six-membered N/O rings are in flattened-boat and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented at a dihedral angle of 18.06 (8)°. In the crystal, weak π–π stacking between the pyridine rings and between the pyridine rings and the naphthalene ring system [centroid–centroid distances = 3.594 (2) and 3.961 (2) Å, respectively] occur. Weak C—H⋯π inter­actions are also observed. These interactions link the molecules into a three-dimensional supramolecular network. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3685025/ /pubmed/23795044 http://dx.doi.org/10.1107/S1600536813012348 Text en © Işıklan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Işıklan, Muhammet
Sonkaya, Ömer
Hökelek, Tuncer
4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title 4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_full 4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_fullStr 4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_full_unstemmed 4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_short 4′,4′,6′,6′-Tetra­chloro-2-(6-methyl­pyridin-2-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_sort 4′,4′,6′,6′-tetra­chloro-2-(6-methyl­pyridin-2-yl)-1h,2h-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685025/
https://www.ncbi.nlm.nih.gov/pubmed/23795044
http://dx.doi.org/10.1107/S1600536813012348
work_keys_str_mv AT isıklanmuhammet 4466tetrachloro26methylpyridin2yl1h2hspironaphtho12e132oxazaphosphinine32135246triazatriphosphinine
AT sonkayaomer 4466tetrachloro26methylpyridin2yl1h2hspironaphtho12e132oxazaphosphinine32135246triazatriphosphinine
AT hokelektuncer 4466tetrachloro26methylpyridin2yl1h2hspironaphtho12e132oxazaphosphinine32135246triazatriphosphinine

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