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6-[(2,4-Di­methyl­anilino)methyl­idene]-2-hy­droxy­cyclo­hexa-2,4-dienone

In the title compound, C(15)H(15)NO(2), the dihedral angle between the aromatic rings is 5.86 (6)°, and an intra­molecular N—H⋯O hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intra­molecular O—H⋯O hydrogen bond also occurs. In the crystal, inversion di...

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Detalles Bibliográficos
Autores principales: Shujah, Shaukat, Ali, Saqib, Zia-ur-Rehman, Tahir, M. Nawaz, Meetsma, Auke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685031/
https://www.ncbi.nlm.nih.gov/pubmed/23795050
http://dx.doi.org/10.1107/S1600536813012233
Descripción
Sumario:In the title compound, C(15)H(15)NO(2), the dihedral angle between the aromatic rings is 5.86 (6)°, and an intra­molecular N—H⋯O hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intra­molecular O—H⋯O hydrogen bond also occurs. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(10) loops. A C—H⋯O inter­action links the dimers into [010] chains and aromatic π–π stacking [centroid–centroid separation = 3.6131 (9) Å] also occurs.