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6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone
In the title compound, C(15)H(15)NO(2), the dihedral angle between the aromatic rings is 5.86 (6)°, and an intramolecular N—H⋯O hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intramolecular O—H⋯O hydrogen bond also occurs. In the crystal, inversion di...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685031/ https://www.ncbi.nlm.nih.gov/pubmed/23795050 http://dx.doi.org/10.1107/S1600536813012233 |
Sumario: | In the title compound, C(15)H(15)NO(2), the dihedral angle between the aromatic rings is 5.86 (6)°, and an intramolecular N—H⋯O hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intramolecular O—H⋯O hydrogen bond also occurs. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(10) loops. A C—H⋯O interaction links the dimers into [010] chains and aromatic π–π stacking [centroid–centroid separation = 3.6131 (9) Å] also occurs. |
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