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2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone
In the title compound, C(14)H(19)ClN(2)O, the diazepine ring adopts a boat conformation. The Cl atom of the chloroacetyl group is trans to the N atom of the diazepine ring. In the crystal, the molecules form chains running along the diagonal of the ac plane through N—H⋯O hydrogen bonds.
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685033/ https://www.ncbi.nlm.nih.gov/pubmed/23795052 http://dx.doi.org/10.1107/S1600536813012324 |
| _version_ | 1782273642507272192 |
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| author | Thiruselvam, V. Rajakumari, D. Deepa Akila, A. Ponnuswamy, S. Ponnuswamy, M. N. |
| author_facet | Thiruselvam, V. Rajakumari, D. Deepa Akila, A. Ponnuswamy, S. Ponnuswamy, M. N. |
| author_sort | Thiruselvam, V. |
| collection | PubMed |
| description | In the title compound, C(14)H(19)ClN(2)O, the diazepine ring adopts a boat conformation. The Cl atom of the chloroacetyl group is trans to the N atom of the diazepine ring. In the crystal, the molecules form chains running along the diagonal of the ac plane through N—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3685033 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36850332013-06-21 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone Thiruselvam, V. Rajakumari, D. Deepa Akila, A. Ponnuswamy, S. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(19)ClN(2)O, the diazepine ring adopts a boat conformation. The Cl atom of the chloroacetyl group is trans to the N atom of the diazepine ring. In the crystal, the molecules form chains running along the diagonal of the ac plane through N—H⋯O hydrogen bonds. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3685033/ /pubmed/23795052 http://dx.doi.org/10.1107/S1600536813012324 Text en © Thiruselvam et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Thiruselvam, V. Rajakumari, D. Deepa Akila, A. Ponnuswamy, S. Ponnuswamy, M. N. 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone |
| title | 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone |
| title_full | 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone |
| title_fullStr | 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone |
| title_full_unstemmed | 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone |
| title_short | 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-1-yl)ethanone |
| title_sort | 2-chloro-1-(2,4,4-trimethyl-2,3,4,5-tetrahydro-1h-1,5-benzodiazepin-1-yl)ethanone |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685033/ https://www.ncbi.nlm.nih.gov/pubmed/23795052 http://dx.doi.org/10.1107/S1600536813012324 |
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