2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole

The title compound, C(24)H(19)ClN(2), crystallizes with two independent mol­ecules in the asymmetric unit. The prop-2-enyl substituents on the imidazole rings adopt similar conformations in the two mol­ecules. The 4-and 5-substituted phenyl rings and the benzene ring make dihedral angles of 67.06 (8...

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Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Marzouk, Adel A. E., Santoyo-Gonzalez, Francisco, Elremaily, Mahmoud A. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685034/
https://www.ncbi.nlm.nih.gov/pubmed/23795053
http://dx.doi.org/10.1107/S1600536813012592
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author Mohamed, Shaaban K.
Akkurt, Mehmet
Marzouk, Adel A. E.
Santoyo-Gonzalez, Francisco
Elremaily, Mahmoud A. A.
author_facet Mohamed, Shaaban K.
Akkurt, Mehmet
Marzouk, Adel A. E.
Santoyo-Gonzalez, Francisco
Elremaily, Mahmoud A. A.
author_sort Mohamed, Shaaban K.
collection PubMed
description The title compound, C(24)H(19)ClN(2), crystallizes with two independent mol­ecules in the asymmetric unit. The prop-2-enyl substituents on the imidazole rings adopt similar conformations in the two mol­ecules. The 4-and 5-substituted phenyl rings and the benzene ring make dihedral angles of 67.06 (8), 5.61 (8) and 41.09 (8)°, respectively, with the imadazole ring in one mol­ecule and 71.53 (8), 28.85 (8) and 41.87 (8)°, respectively, in the other. The crystal structure features C—H⋯π inter­actions and weak π–π stacking inter­actions [centroid–centroid distances = 3.6937 (10) and 4.0232 (10) Å] between the chloro­phenyl rings, which form a three-dimensional supramolecular structure.
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spelling pubmed-36850342013-06-21 2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole Mohamed, Shaaban K. Akkurt, Mehmet Marzouk, Adel A. E. Santoyo-Gonzalez, Francisco Elremaily, Mahmoud A. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(19)ClN(2), crystallizes with two independent mol­ecules in the asymmetric unit. The prop-2-enyl substituents on the imidazole rings adopt similar conformations in the two mol­ecules. The 4-and 5-substituted phenyl rings and the benzene ring make dihedral angles of 67.06 (8), 5.61 (8) and 41.09 (8)°, respectively, with the imadazole ring in one mol­ecule and 71.53 (8), 28.85 (8) and 41.87 (8)°, respectively, in the other. The crystal structure features C—H⋯π inter­actions and weak π–π stacking inter­actions [centroid–centroid distances = 3.6937 (10) and 4.0232 (10) Å] between the chloro­phenyl rings, which form a three-dimensional supramolecular structure. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3685034/ /pubmed/23795053 http://dx.doi.org/10.1107/S1600536813012592 Text en © Mohamed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohamed, Shaaban K.
Akkurt, Mehmet
Marzouk, Adel A. E.
Santoyo-Gonzalez, Francisco
Elremaily, Mahmoud A. A.
2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title 2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_full 2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_fullStr 2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_full_unstemmed 2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_short 2-(4-Chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_sort 2-(4-chloro­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685034/
https://www.ncbi.nlm.nih.gov/pubmed/23795053
http://dx.doi.org/10.1107/S1600536813012592
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