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N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate
The title compound, C(14)H(13)N(3)O(3)·H(2)O, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, the lattice water molecule plays a major role in the supramolecular architecture by interconne...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685038/ https://www.ncbi.nlm.nih.gov/pubmed/23795057 http://dx.doi.org/10.1107/S160053681301235X |
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author | Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra |
author_facet | Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra |
author_sort | Prasanna, M. K. |
collection | PubMed |
description | The title compound, C(14)H(13)N(3)O(3)·H(2)O, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, the lattice water molecule plays a major role in the supramolecular architecture by interconnecting adjacent molecules into a three-dimensional netwrok by means of O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding interactions. The structure also features two non-classical C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3685038 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36850382013-06-21 N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(13)N(3)O(3)·H(2)O, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, the lattice water molecule plays a major role in the supramolecular architecture by interconnecting adjacent molecules into a three-dimensional netwrok by means of O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding interactions. The structure also features two non-classical C—H⋯O interactions. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3685038/ /pubmed/23795057 http://dx.doi.org/10.1107/S160053681301235X Text en © Prasanna et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Prasanna, M. K. Sithambaresan, M. Pradeepkumar, K. Kurup, M. R. Prathapachandra N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate |
title |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate |
title_full |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate |
title_fullStr |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate |
title_full_unstemmed |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate |
title_short |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate |
title_sort | n′-[(e)-2-hydroxy-5-methoxybenzylidene]pyridine-4-carbohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685038/ https://www.ncbi.nlm.nih.gov/pubmed/23795057 http://dx.doi.org/10.1107/S160053681301235X |
work_keys_str_mv | AT prasannamk ne2hydroxy5methoxybenzylidenepyridine4carbohydrazidemonohydrate AT sithambaresanm ne2hydroxy5methoxybenzylidenepyridine4carbohydrazidemonohydrate AT pradeepkumark ne2hydroxy5methoxybenzylidenepyridine4carbohydrazidemonohydrate AT kurupmrprathapachandra ne2hydroxy5methoxybenzylidenepyridine4carbohydrazidemonohydrate |