8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol

The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these...

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Detalles Bibliográficos
Autores principales: Kantar, Esen Nur, Köysal, Yavuz, Akdemir, Nesuhi, Ağar, Ayşen Alaman, Soylu, Mustafa Serkan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685040/
https://www.ncbi.nlm.nih.gov/pubmed/23795059
http://dx.doi.org/10.1107/S1600536813012579
Descripción
Sumario:The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4).

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