8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol

The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these...

Descripción completa

Detalles Bibliográficos
Autores principales: Kantar, Esen Nur, Köysal, Yavuz, Akdemir, Nesuhi, Ağar, Ayşen Alaman, Soylu, Mustafa Serkan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685040/
https://www.ncbi.nlm.nih.gov/pubmed/23795059
http://dx.doi.org/10.1107/S1600536813012579
_version_ 1782273644074893312
author Kantar, Esen Nur
Köysal, Yavuz
Akdemir, Nesuhi
Ağar, Ayşen Alaman
Soylu, Mustafa Serkan
author_facet Kantar, Esen Nur
Köysal, Yavuz
Akdemir, Nesuhi
Ağar, Ayşen Alaman
Soylu, Mustafa Serkan
author_sort Kantar, Esen Nur
collection PubMed
description The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4).
format Online
Article
Text
id pubmed-3685040
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36850402013-06-21 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol Kantar, Esen Nur Köysal, Yavuz Akdemir, Nesuhi Ağar, Ayşen Alaman Soylu, Mustafa Serkan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4). International Union of Crystallography 2013-05-15 /pmc/articles/PMC3685040/ /pubmed/23795059 http://dx.doi.org/10.1107/S1600536813012579 Text en © Kantar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kantar, Esen Nur
Köysal, Yavuz
Akdemir, Nesuhi
Ağar, Ayşen Alaman
Soylu, Mustafa Serkan
8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_full 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_fullStr 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_full_unstemmed 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_short 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_sort 8-{(e)-[(4-chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685040/
https://www.ncbi.nlm.nih.gov/pubmed/23795059
http://dx.doi.org/10.1107/S1600536813012579
work_keys_str_mv AT kantaresennur 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol
AT koysalyavuz 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol
AT akdemirnesuhi 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol
AT agaraysenalaman 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol
AT soylumustafaserkan 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol

Ejemplares similares