Cargando…
8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol
The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intramolecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexahydropyridoquinoline unit, as well as the two methyl groups bonded to one of these...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685040/ https://www.ncbi.nlm.nih.gov/pubmed/23795059 http://dx.doi.org/10.1107/S1600536813012579 |
_version_ | 1782273644074893312 |
---|---|
author | Kantar, Esen Nur Köysal, Yavuz Akdemir, Nesuhi Ağar, Ayşen Alaman Soylu, Mustafa Serkan |
author_facet | Kantar, Esen Nur Köysal, Yavuz Akdemir, Nesuhi Ağar, Ayşen Alaman Soylu, Mustafa Serkan |
author_sort | Kantar, Esen Nur |
collection | PubMed |
description | The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intramolecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexahydropyridoquinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4). |
format | Online Article Text |
id | pubmed-3685040 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36850402013-06-21 8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol Kantar, Esen Nur Köysal, Yavuz Akdemir, Nesuhi Ağar, Ayşen Alaman Soylu, Mustafa Serkan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intramolecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexahydropyridoquinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4). International Union of Crystallography 2013-05-15 /pmc/articles/PMC3685040/ /pubmed/23795059 http://dx.doi.org/10.1107/S1600536813012579 Text en © Kantar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kantar, Esen Nur Köysal, Yavuz Akdemir, Nesuhi Ağar, Ayşen Alaman Soylu, Mustafa Serkan 8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol |
title | 8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol |
title_full | 8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol |
title_fullStr | 8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol |
title_full_unstemmed | 8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol |
title_short | 8-{(E)-[(4-Chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol |
title_sort | 8-{(e)-[(4-chlorophenyl)imino]methyl}-1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685040/ https://www.ncbi.nlm.nih.gov/pubmed/23795059 http://dx.doi.org/10.1107/S1600536813012579 |
work_keys_str_mv | AT kantaresennur 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol AT koysalyavuz 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol AT akdemirnesuhi 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol AT agaraysenalaman 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol AT soylumustafaserkan 8e4chlorophenyliminomethyl1177tetramethyl123567hexahydropyrido321ijquinolin9ol |