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8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol

The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these...

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Autores principales: Kantar, Esen Nur, Köysal, Yavuz, Akdemir, Nesuhi, Ağar, Ayşen Alaman, Soylu, Mustafa Serkan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685040/
https://www.ncbi.nlm.nih.gov/pubmed/23795059
http://dx.doi.org/10.1107/S1600536813012579
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author Kantar, Esen Nur
Köysal, Yavuz
Akdemir, Nesuhi
Ağar, Ayşen Alaman
Soylu, Mustafa Serkan
author_facet Kantar, Esen Nur
Köysal, Yavuz
Akdemir, Nesuhi
Ağar, Ayşen Alaman
Soylu, Mustafa Serkan
author_sort Kantar, Esen Nur
collection PubMed
description The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4).
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spelling pubmed-36850402013-06-21 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol Kantar, Esen Nur Köysal, Yavuz Akdemir, Nesuhi Ağar, Ayşen Alaman Soylu, Mustafa Serkan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base, C(23)H(27)ClN(2)O adopts the phenol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa­hydro­pyrido­quinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4). International Union of Crystallography 2013-05-15 /pmc/articles/PMC3685040/ /pubmed/23795059 http://dx.doi.org/10.1107/S1600536813012579 Text en © Kantar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kantar, Esen Nur
Köysal, Yavuz
Akdemir, Nesuhi
Ağar, Ayşen Alaman
Soylu, Mustafa Serkan
8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_full 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_fullStr 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_full_unstemmed 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_short 8-{(E)-[(4-Chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
title_sort 8-{(e)-[(4-chloro­phen­yl)imino]­meth­yl}-1,1,7,7-tetra­methyl-1,2,3,5,6,7-hexa­hydro­pyrido[3,2,1-ij]quinolin-9-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685040/
https://www.ncbi.nlm.nih.gov/pubmed/23795059
http://dx.doi.org/10.1107/S1600536813012579
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