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Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate
In the title compound, C(24)H(23)N(3)O(2), the benzimidazole ring system makes dihedral angles of 7.28 (5) and 67.17 (5)°, respectively, with the planes of the benzene and phenyl rings, which in turn make a dihedral angle of 69.77 (6)°. In the crystal, molecules are connected by C—H⋯N and C—H⋯O int...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685043/ https://www.ncbi.nlm.nih.gov/pubmed/23795062 http://dx.doi.org/10.1107/S1600536813012440 |
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author | Yeong, Keng Yoon Ali, Mohamed Ashraf Choon, Tan Soo Rosli, Mohd Mustaqim Razak, Ibrahim Abdul |
author_facet | Yeong, Keng Yoon Ali, Mohamed Ashraf Choon, Tan Soo Rosli, Mohd Mustaqim Razak, Ibrahim Abdul |
author_sort | Yeong, Keng Yoon |
collection | PubMed |
description | In the title compound, C(24)H(23)N(3)O(2), the benzimidazole ring system makes dihedral angles of 7.28 (5) and 67.17 (5)°, respectively, with the planes of the benzene and phenyl rings, which in turn make a dihedral angle of 69.77 (6)°. In the crystal, molecules are connected by C—H⋯N and C—H⋯O interactions, forming a layer parallel to the bc plane. A π–π interaction, with a centroid–centroid distance of 3.656 (1) Å, is observed in the layer. |
format | Online Article Text |
id | pubmed-3685043 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36850432013-06-21 Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate Yeong, Keng Yoon Ali, Mohamed Ashraf Choon, Tan Soo Rosli, Mohd Mustaqim Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(23)N(3)O(2), the benzimidazole ring system makes dihedral angles of 7.28 (5) and 67.17 (5)°, respectively, with the planes of the benzene and phenyl rings, which in turn make a dihedral angle of 69.77 (6)°. In the crystal, molecules are connected by C—H⋯N and C—H⋯O interactions, forming a layer parallel to the bc plane. A π–π interaction, with a centroid–centroid distance of 3.656 (1) Å, is observed in the layer. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3685043/ /pubmed/23795062 http://dx.doi.org/10.1107/S1600536813012440 Text en © Yeong et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yeong, Keng Yoon Ali, Mohamed Ashraf Choon, Tan Soo Rosli, Mohd Mustaqim Razak, Ibrahim Abdul Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate |
title | Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate |
title_full | Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate |
title_fullStr | Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate |
title_full_unstemmed | Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate |
title_short | Ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1H-benzimidazole-5-carboxylate |
title_sort | ethyl 2-[4-(dimethylamino)phenyl]-1-phenyl-1h-benzimidazole-5-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685043/ https://www.ncbi.nlm.nih.gov/pubmed/23795062 http://dx.doi.org/10.1107/S1600536813012440 |
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