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Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate

In the title compound, C(24)H(23)N(3)O(2), the benzimidazole ring system makes dihedral angles of 7.28 (5) and 67.17 (5)°, respectively, with the planes of the benzene and phenyl rings, which in turn make a dihedral angle of 69.77 (6)°. In the crystal, mol­ecules are connected by C—H⋯N and C—H⋯O int...

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Autores principales: Yeong, Keng Yoon, Ali, Mohamed Ashraf, Choon, Tan Soo, Rosli, Mohd Mustaqim, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685043/
https://www.ncbi.nlm.nih.gov/pubmed/23795062
http://dx.doi.org/10.1107/S1600536813012440
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author Yeong, Keng Yoon
Ali, Mohamed Ashraf
Choon, Tan Soo
Rosli, Mohd Mustaqim
Razak, Ibrahim Abdul
author_facet Yeong, Keng Yoon
Ali, Mohamed Ashraf
Choon, Tan Soo
Rosli, Mohd Mustaqim
Razak, Ibrahim Abdul
author_sort Yeong, Keng Yoon
collection PubMed
description In the title compound, C(24)H(23)N(3)O(2), the benzimidazole ring system makes dihedral angles of 7.28 (5) and 67.17 (5)°, respectively, with the planes of the benzene and phenyl rings, which in turn make a dihedral angle of 69.77 (6)°. In the crystal, mol­ecules are connected by C—H⋯N and C—H⋯O inter­actions, forming a layer parallel to the bc plane. A π–π inter­action, with a centroid–centroid distance of 3.656 (1) Å, is observed in the layer.
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spelling pubmed-36850432013-06-21 Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate Yeong, Keng Yoon Ali, Mohamed Ashraf Choon, Tan Soo Rosli, Mohd Mustaqim Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(23)N(3)O(2), the benzimidazole ring system makes dihedral angles of 7.28 (5) and 67.17 (5)°, respectively, with the planes of the benzene and phenyl rings, which in turn make a dihedral angle of 69.77 (6)°. In the crystal, mol­ecules are connected by C—H⋯N and C—H⋯O inter­actions, forming a layer parallel to the bc plane. A π–π inter­action, with a centroid–centroid distance of 3.656 (1) Å, is observed in the layer. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3685043/ /pubmed/23795062 http://dx.doi.org/10.1107/S1600536813012440 Text en © Yeong et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yeong, Keng Yoon
Ali, Mohamed Ashraf
Choon, Tan Soo
Rosli, Mohd Mustaqim
Razak, Ibrahim Abdul
Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate
title Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate
title_full Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate
title_fullStr Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate
title_full_unstemmed Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate
title_short Ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1H-benzimidazole-5-carboxyl­ate
title_sort ethyl 2-[4-(di­methyl­amino)­phen­yl]-1-phenyl-1h-benzimidazole-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685043/
https://www.ncbi.nlm.nih.gov/pubmed/23795062
http://dx.doi.org/10.1107/S1600536813012440
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