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8,13,26-Trioxa-23-thia-21-azapentacyclo[18.6.0.0(2,7).0(14,19).0(21,25)]hexacosa-2(7),3,5,14,16,18-hexaene
In the title compound, C(21)H(23)NO(3)S, both the thiazole and oxazolidine rings adopt twist conformations. The mean plane of the thiazole ring makes a dihedral angle of 61.02 (7)° with the oxazolidine ring mean plane, and dihedral angles of 22.72 (6) and 75.07 (6)° with the benzene rings. The ben...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685049/ https://www.ncbi.nlm.nih.gov/pubmed/23795068 http://dx.doi.org/10.1107/S1600536813012804 |
| Sumario: | In the title compound, C(21)H(23)NO(3)S, both the thiazole and oxazolidine rings adopt twist conformations. The mean plane of the thiazole ring makes a dihedral angle of 61.02 (7)° with the oxazolidine ring mean plane, and dihedral angles of 22.72 (6) and 75.07 (6)° with the benzene rings. The benzene rings are almost perpendicular to one another, making a dihedral angle of 89.14 (6)°. There are bifurcated intramolecular C—H⋯O hydrogen bonds in the molecular structure. In the crystal, molecules are linked via C—H⋯π interactions, forming chains propagating along [100]. |
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