8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene

In the title compound, C(21)H(23)NO(3)S, both the thia­zole and oxazolidine rings adopt twist conformations. The mean plane of the thia­zole ring makes a dihedral angle of 61.02 (7)° with the oxazolidine ring mean plane, and dihedral angles of 22.72 (6) and 75.07 (6)° with the benzene rings. The ben...

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Autores principales: Devi, Seenivasan Karthiga, Srinivasan, Thothadri, Purushothaman, Santhanagopalan, Raghunathan, Raghavachary, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685049/
https://www.ncbi.nlm.nih.gov/pubmed/23795068
http://dx.doi.org/10.1107/S1600536813012804
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author Devi, Seenivasan Karthiga
Srinivasan, Thothadri
Purushothaman, Santhanagopalan
Raghunathan, Raghavachary
Velmurugan, Devadasan
author_facet Devi, Seenivasan Karthiga
Srinivasan, Thothadri
Purushothaman, Santhanagopalan
Raghunathan, Raghavachary
Velmurugan, Devadasan
author_sort Devi, Seenivasan Karthiga
collection PubMed
description In the title compound, C(21)H(23)NO(3)S, both the thia­zole and oxazolidine rings adopt twist conformations. The mean plane of the thia­zole ring makes a dihedral angle of 61.02 (7)° with the oxazolidine ring mean plane, and dihedral angles of 22.72 (6) and 75.07 (6)° with the benzene rings. The benzene rings are almost perpendicular to one another, making a dihedral angle of 89.14 (6)°. There are bifurcated intra­molecular C—H⋯O hydrogen bonds in the mol­ecular structure. In the crystal, mol­ecules are linked via C—H⋯π inter­actions, forming chains propagating along [100].
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spelling pubmed-36850492013-06-21 8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene Devi, Seenivasan Karthiga Srinivasan, Thothadri Purushothaman, Santhanagopalan Raghunathan, Raghavachary Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(23)NO(3)S, both the thia­zole and oxazolidine rings adopt twist conformations. The mean plane of the thia­zole ring makes a dihedral angle of 61.02 (7)° with the oxazolidine ring mean plane, and dihedral angles of 22.72 (6) and 75.07 (6)° with the benzene rings. The benzene rings are almost perpendicular to one another, making a dihedral angle of 89.14 (6)°. There are bifurcated intra­molecular C—H⋯O hydrogen bonds in the mol­ecular structure. In the crystal, mol­ecules are linked via C—H⋯π inter­actions, forming chains propagating along [100]. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3685049/ /pubmed/23795068 http://dx.doi.org/10.1107/S1600536813012804 Text en © Devi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Devi, Seenivasan Karthiga
Srinivasan, Thothadri
Purushothaman, Santhanagopalan
Raghunathan, Raghavachary
Velmurugan, Devadasan
8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene
title 8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene
title_full 8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene
title_fullStr 8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene
title_full_unstemmed 8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene
title_short 8,13,26-Trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene
title_sort 8,13,26-trioxa-23-thia-21-aza­penta­cyclo­[18.6.0.0(2,7).0(14,19).0(21,25)]hexa­cosa-2(7),3,5,14,16,18-hexa­ene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685049/
https://www.ncbi.nlm.nih.gov/pubmed/23795068
http://dx.doi.org/10.1107/S1600536813012804
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