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N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)

In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearl...

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Detalles Bibliográficos
Autor principal: Tiritiris, Ioannis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685056/
https://www.ncbi.nlm.nih.gov/pubmed/23795075
http://dx.doi.org/10.1107/S1600536813012786
Descripción
Sumario:In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearly ideal trigonal–planar geometry [N—C—N angles = 117.7 (4), 120.9 (3) and 121.4 (3)°] and the positive charge is delocalized in the CN(3) plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety all have values close to a typical single bond [1.452 (5)–1.484 (6) Å]. In the crystal, C—H⋯π inter­actions are present between guanidinium H atoms and the phenyl rings of both tetra­phenyl­borate ions. This leads to the formation of a two-dimensional supramolecular pattern along the ab plane.