Cargando…

N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)

In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearl...

Descripción completa

Detalles Bibliográficos
Autor principal: Tiritiris, Ioannis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685056/
https://www.ncbi.nlm.nih.gov/pubmed/23795075
http://dx.doi.org/10.1107/S1600536813012786
_version_ 1782273647705063424
author Tiritiris, Ioannis
author_facet Tiritiris, Ioannis
author_sort Tiritiris, Ioannis
collection PubMed
description In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearly ideal trigonal–planar geometry [N—C—N angles = 117.7 (4), 120.9 (3) and 121.4 (3)°] and the positive charge is delocalized in the CN(3) plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety all have values close to a typical single bond [1.452 (5)–1.484 (6) Å]. In the crystal, C—H⋯π inter­actions are present between guanidinium H atoms and the phenyl rings of both tetra­phenyl­borate ions. This leads to the formation of a two-dimensional supramolecular pattern along the ab plane.
format Online
Article
Text
id pubmed-3685056
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36850562013-06-21 N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate) Tiritiris, Ioannis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearly ideal trigonal–planar geometry [N—C—N angles = 117.7 (4), 120.9 (3) and 121.4 (3)°] and the positive charge is delocalized in the CN(3) plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety all have values close to a typical single bond [1.452 (5)–1.484 (6) Å]. In the crystal, C—H⋯π inter­actions are present between guanidinium H atoms and the phenyl rings of both tetra­phenyl­borate ions. This leads to the formation of a two-dimensional supramolecular pattern along the ab plane. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685056/ /pubmed/23795075 http://dx.doi.org/10.1107/S1600536813012786 Text en © Ioannis Tiritiris 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiritiris, Ioannis
N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)
title N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)
title_full N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)
title_fullStr N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)
title_full_unstemmed N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)
title_short N-[3-(Benzyl­dimethyl­aza­nium­yl)prop­yl]-N′,N′,N′′,N′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)
title_sort n-[3-(benzyl­dimethyl­aza­nium­yl)prop­yl]-n′,n′,n′′,n′′-tetra­methyl­guanidinium bis­(tetra­phenyl­borate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685056/
https://www.ncbi.nlm.nih.gov/pubmed/23795075
http://dx.doi.org/10.1107/S1600536813012786
work_keys_str_mv AT tiritirisioannis n3benzyldimethylazaniumylpropylnnnntetramethylguanidiniumbistetraphenylborate