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N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate)
In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearl...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685056/ https://www.ncbi.nlm.nih.gov/pubmed/23795075 http://dx.doi.org/10.1107/S1600536813012786 |
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author | Tiritiris, Ioannis |
author_facet | Tiritiris, Ioannis |
author_sort | Tiritiris, Ioannis |
collection | PubMed |
description | In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearly ideal trigonal–planar geometry [N—C—N angles = 117.7 (4), 120.9 (3) and 121.4 (3)°] and the positive charge is delocalized in the CN(3) plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety all have values close to a typical single bond [1.452 (5)–1.484 (6) Å]. In the crystal, C—H⋯π interactions are present between guanidinium H atoms and the phenyl rings of both tetraphenylborate ions. This leads to the formation of a two-dimensional supramolecular pattern along the ab plane. |
format | Online Article Text |
id | pubmed-3685056 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36850562013-06-21 N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate) Tiritiris, Ioannis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title salt, C(17)H(32)N(4) (2+)·2C(24)H(20)B(−), the C—N bond lengths in the CN(3) unit of the guanidinium ion are 1.323 (4), 1.336 (5) and 1.337 (5) Å, indicating partial double-bond character in each. The C atom of this unit is bonded to the three N atoms in a nearly ideal trigonal–planar geometry [N—C—N angles = 117.7 (4), 120.9 (3) and 121.4 (3)°] and the positive charge is delocalized in the CN(3) plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety all have values close to a typical single bond [1.452 (5)–1.484 (6) Å]. In the crystal, C—H⋯π interactions are present between guanidinium H atoms and the phenyl rings of both tetraphenylborate ions. This leads to the formation of a two-dimensional supramolecular pattern along the ab plane. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685056/ /pubmed/23795075 http://dx.doi.org/10.1107/S1600536813012786 Text en © Ioannis Tiritiris 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tiritiris, Ioannis N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate) |
title |
N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate) |
title_full |
N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate) |
title_fullStr |
N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate) |
title_full_unstemmed |
N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate) |
title_short |
N-[3-(Benzyldimethylazaniumyl)propyl]-N′,N′,N′′,N′′-tetramethylguanidinium bis(tetraphenylborate) |
title_sort | n-[3-(benzyldimethylazaniumyl)propyl]-n′,n′,n′′,n′′-tetramethylguanidinium bis(tetraphenylborate) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685056/ https://www.ncbi.nlm.nih.gov/pubmed/23795075 http://dx.doi.org/10.1107/S1600536813012786 |
work_keys_str_mv | AT tiritirisioannis n3benzyldimethylazaniumylpropylnnnntetramethylguanidiniumbistetraphenylborate |