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1-[4-(Dimethylamino)benzylidene]-4-o-tolylthiosemicarbazide
The asymmetric unit of the title compound, C(17)H(20)N(4)S, contains two independent molecules, the main difference between them being the dihedral angles between the benzene rings [19.99 (17) and 9.72 (17)°]. The molecules both have a trans conformation about the C=N double bond and intramolecul...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685061/ https://www.ncbi.nlm.nih.gov/pubmed/23795080 http://dx.doi.org/10.1107/S1600536813012890 |
Sumario: | The asymmetric unit of the title compound, C(17)H(20)N(4)S, contains two independent molecules, the main difference between them being the dihedral angles between the benzene rings [19.99 (17) and 9.72 (17)°]. The molecules both have a trans conformation about the C=N double bond and intramolecular C—H⋯S and N—H⋯N hydrogen bonds are observed in both molecules. In the crystal, molecules are linked by weak N—H⋯S hydrogen bonds with graph-set motif R (2) (2)(8). In each molecule, all but one of the N atoms and both the S atoms are involved in hydrogen bonding. |
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