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1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide

The asymmetric unit of the title compound, C(17)H(20)N(4)S, contains two independent mol­ecules, the main difference between them being the dihedral angles between the benzene rings [19.99 (17) and 9.72 (17)°]. The mol­ecules both have a trans conformation about the C=N double bond and intra­molecul...

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Detalles Bibliográficos
Autores principales: Huang, Rui-Yun, Xu, Qin-Juan, Lin, Li-Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685061/
https://www.ncbi.nlm.nih.gov/pubmed/23795080
http://dx.doi.org/10.1107/S1600536813012890
Descripción
Sumario:The asymmetric unit of the title compound, C(17)H(20)N(4)S, contains two independent mol­ecules, the main difference between them being the dihedral angles between the benzene rings [19.99 (17) and 9.72 (17)°]. The mol­ecules both have a trans conformation about the C=N double bond and intra­molecular C—H⋯S and N—H⋯N hydrogen bonds are observed in both mol­ecules. In the crystal, mol­ecules are linked by weak N—H⋯S hydrogen bonds with graph-set motif R (2) (2)(8). In each mol­ecule, all but one of the N atoms and both the S atoms are involved in hydrogen bonding.