1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide

The asymmetric unit of the title compound, C(17)H(20)N(4)S, contains two independent mol­ecules, the main difference between them being the dihedral angles between the benzene rings [19.99 (17) and 9.72 (17)°]. The mol­ecules both have a trans conformation about the C=N double bond and intra­molecul...

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Detalles Bibliográficos
Autores principales: Huang, Rui-Yun, Xu, Qin-Juan, Lin, Li-Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685061/
https://www.ncbi.nlm.nih.gov/pubmed/23795080
http://dx.doi.org/10.1107/S1600536813012890
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author Huang, Rui-Yun
Xu, Qin-Juan
Lin, Li-Rong
author_facet Huang, Rui-Yun
Xu, Qin-Juan
Lin, Li-Rong
author_sort Huang, Rui-Yun
collection PubMed
description The asymmetric unit of the title compound, C(17)H(20)N(4)S, contains two independent mol­ecules, the main difference between them being the dihedral angles between the benzene rings [19.99 (17) and 9.72 (17)°]. The mol­ecules both have a trans conformation about the C=N double bond and intra­molecular C—H⋯S and N—H⋯N hydrogen bonds are observed in both mol­ecules. In the crystal, mol­ecules are linked by weak N—H⋯S hydrogen bonds with graph-set motif R (2) (2)(8). In each mol­ecule, all but one of the N atoms and both the S atoms are involved in hydrogen bonding.
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spelling pubmed-36850612013-06-21 1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide Huang, Rui-Yun Xu, Qin-Juan Lin, Li-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(17)H(20)N(4)S, contains two independent mol­ecules, the main difference between them being the dihedral angles between the benzene rings [19.99 (17) and 9.72 (17)°]. The mol­ecules both have a trans conformation about the C=N double bond and intra­molecular C—H⋯S and N—H⋯N hydrogen bonds are observed in both mol­ecules. In the crystal, mol­ecules are linked by weak N—H⋯S hydrogen bonds with graph-set motif R (2) (2)(8). In each mol­ecule, all but one of the N atoms and both the S atoms are involved in hydrogen bonding. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685061/ /pubmed/23795080 http://dx.doi.org/10.1107/S1600536813012890 Text en © Huang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Huang, Rui-Yun
Xu, Qin-Juan
Lin, Li-Rong
1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide
title 1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide
title_full 1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide
title_fullStr 1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide
title_full_unstemmed 1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide
title_short 1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide
title_sort 1-[4-(di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685061/
https://www.ncbi.nlm.nih.gov/pubmed/23795080
http://dx.doi.org/10.1107/S1600536813012890
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AT xuqinjuan 14dimethylaminobenzylidene4otolylthiosemicarbazide
AT linlirong 14dimethylaminobenzylidene4otolylthiosemicarbazide

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