Cargando…
3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide]
In the title compound, C(40)H(30)Cl(2)N(2)O(4), the two benzene rings of the biphenyl unit are twisted with respect to each other, making a dihedral angle of 73.07 (4)°. The benzene rings of the benzamide groups form dihedral angles of 77.09 (5) and 55.48 (6)° with the central biphenyl moiety. In th...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685066/ https://www.ncbi.nlm.nih.gov/pubmed/23795085 http://dx.doi.org/10.1107/S160053681301009X |
_version_ | 1782273649988861952 |
---|---|
author | Rajadurai, Raj Padmanabhan, Ramar Meenakshi Sundaram, Soma Sundaram Ananthan, Sarkkarai |
author_facet | Rajadurai, Raj Padmanabhan, Ramar Meenakshi Sundaram, Soma Sundaram Ananthan, Sarkkarai |
author_sort | Rajadurai, Raj |
collection | PubMed |
description | In the title compound, C(40)H(30)Cl(2)N(2)O(4), the two benzene rings of the biphenyl unit are twisted with respect to each other, making a dihedral angle of 73.07 (4)°. The benzene rings of the benzamide groups form dihedral angles of 77.09 (5) and 55.48 (6)° with the central biphenyl moiety. In the crystal, molecules are linked through N—H⋯O hydrogen bonds to form a fused R (2) (2)(38) ring motif which forms a supermolecular ribbon network extending along the [100] plane. In the two 4-chlorophenyl rings, the five C atoms and their attached H atoms are disordered over two sets of sites, with site-occupancy factors of 0.657 (15):0.343 (15) and 0.509 (13):0.491 (13). |
format | Online Article Text |
id | pubmed-3685066 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36850662013-06-21 3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide] Rajadurai, Raj Padmanabhan, Ramar Meenakshi Sundaram, Soma Sundaram Ananthan, Sarkkarai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(40)H(30)Cl(2)N(2)O(4), the two benzene rings of the biphenyl unit are twisted with respect to each other, making a dihedral angle of 73.07 (4)°. The benzene rings of the benzamide groups form dihedral angles of 77.09 (5) and 55.48 (6)° with the central biphenyl moiety. In the crystal, molecules are linked through N—H⋯O hydrogen bonds to form a fused R (2) (2)(38) ring motif which forms a supermolecular ribbon network extending along the [100] plane. In the two 4-chlorophenyl rings, the five C atoms and their attached H atoms are disordered over two sets of sites, with site-occupancy factors of 0.657 (15):0.343 (15) and 0.509 (13):0.491 (13). International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685066/ /pubmed/23795085 http://dx.doi.org/10.1107/S160053681301009X Text en © Rajadurai et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rajadurai, Raj Padmanabhan, Ramar Meenakshi Sundaram, Soma Sundaram Ananthan, Sarkkarai 3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide] |
title | 3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide] |
title_full | 3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide] |
title_fullStr | 3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide] |
title_full_unstemmed | 3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide] |
title_short | 3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide] |
title_sort | 3,3′-{[(biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[n-(4-chlorophenyl)benzamide] |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685066/ https://www.ncbi.nlm.nih.gov/pubmed/23795085 http://dx.doi.org/10.1107/S160053681301009X |
work_keys_str_mv | AT rajadurairaj 33biphenyl22diylbismethylenebisoxybisn4chlorophenylbenzamide AT padmanabhanramar 33biphenyl22diylbismethylenebisoxybisn4chlorophenylbenzamide AT meenakshisundaramsomasundaram 33biphenyl22diylbismethylenebisoxybisn4chlorophenylbenzamide AT ananthansarkkarai 33biphenyl22diylbismethylenebisoxybisn4chlorophenylbenzamide |