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3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide]

In the title compound, C(40)H(30)Cl(2)N(2)O(4), the two benzene rings of the biphenyl unit are twisted with respect to each other, making a dihedral angle of 73.07 (4)°. The benzene rings of the benzamide groups form dihedral angles of 77.09 (5) and 55.48 (6)° with the central biphenyl moiety. In th...

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Autores principales: Rajadurai, Raj, Padmanabhan, Ramar, Meenakshi Sundaram, Soma Sundaram, Ananthan, Sarkkarai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685066/
https://www.ncbi.nlm.nih.gov/pubmed/23795085
http://dx.doi.org/10.1107/S160053681301009X
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author Rajadurai, Raj
Padmanabhan, Ramar
Meenakshi Sundaram, Soma Sundaram
Ananthan, Sarkkarai
author_facet Rajadurai, Raj
Padmanabhan, Ramar
Meenakshi Sundaram, Soma Sundaram
Ananthan, Sarkkarai
author_sort Rajadurai, Raj
collection PubMed
description In the title compound, C(40)H(30)Cl(2)N(2)O(4), the two benzene rings of the biphenyl unit are twisted with respect to each other, making a dihedral angle of 73.07 (4)°. The benzene rings of the benzamide groups form dihedral angles of 77.09 (5) and 55.48 (6)° with the central biphenyl moiety. In the crystal, mol­ecules are linked through N—H⋯O hydrogen bonds to form a fused R (2) (2)(38) ring motif which forms a supermolecular ribbon network extending along the [100] plane. In the two 4-chloro­phenyl rings, the five C atoms and their attached H atoms are disordered over two sets of sites, with site-occupancy factors of 0.657 (15):0.343 (15) and 0.509 (13):0.491 (13).
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spelling pubmed-36850662013-06-21 3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide] Rajadurai, Raj Padmanabhan, Ramar Meenakshi Sundaram, Soma Sundaram Ananthan, Sarkkarai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(40)H(30)Cl(2)N(2)O(4), the two benzene rings of the biphenyl unit are twisted with respect to each other, making a dihedral angle of 73.07 (4)°. The benzene rings of the benzamide groups form dihedral angles of 77.09 (5) and 55.48 (6)° with the central biphenyl moiety. In the crystal, mol­ecules are linked through N—H⋯O hydrogen bonds to form a fused R (2) (2)(38) ring motif which forms a supermolecular ribbon network extending along the [100] plane. In the two 4-chloro­phenyl rings, the five C atoms and their attached H atoms are disordered over two sets of sites, with site-occupancy factors of 0.657 (15):0.343 (15) and 0.509 (13):0.491 (13). International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685066/ /pubmed/23795085 http://dx.doi.org/10.1107/S160053681301009X Text en © Rajadurai et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rajadurai, Raj
Padmanabhan, Ramar
Meenakshi Sundaram, Soma Sundaram
Ananthan, Sarkkarai
3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide]
title 3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide]
title_full 3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide]
title_fullStr 3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide]
title_full_unstemmed 3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide]
title_short 3,3′-{[(Biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[N-(4-chloro­phen­yl)benzamide]
title_sort 3,3′-{[(biphenyl-2,2′-di­yl)bis­(methyl­ene)]bis­(­oxy)}bis­[n-(4-chloro­phen­yl)benzamide]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685066/
https://www.ncbi.nlm.nih.gov/pubmed/23795085
http://dx.doi.org/10.1107/S160053681301009X
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