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1-[2-(Trityloxy)phenyl]ethanone
In the title compound, C(27)H(22)O(2), the acetyl group is nearly coplanar with the the ring to which it attacted [O—C—C—C torsion angle = −5.5 (3)°]. The three phenyl groups of the triphenylmethyl substituent are mutually nearly perpendicular, making dihedral angles of 89.87 (11) and 78.29 (11) a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685069/ https://www.ncbi.nlm.nih.gov/pubmed/23795088 http://dx.doi.org/10.1107/S1600536813012956 |
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author | Zhao, Pengying |
author_facet | Zhao, Pengying |
author_sort | Zhao, Pengying |
collection | PubMed |
description | In the title compound, C(27)H(22)O(2), the acetyl group is nearly coplanar with the the ring to which it attacted [O—C—C—C torsion angle = −5.5 (3)°]. The three phenyl groups of the triphenylmethyl substituent are mutually nearly perpendicular, making dihedral angles of 89.87 (11) and 78.29 (11) and 60.34 (11)°. Two intramolecular C—H⋯ O hydrogen bonds occur. In the crystal, C—H⋯ O hydrogen bonds link the moleclues into chains along the b-axis direction. |
format | Online Article Text |
id | pubmed-3685069 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36850692013-06-21 1-[2-(Trityloxy)phenyl]ethanone Zhao, Pengying Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(22)O(2), the acetyl group is nearly coplanar with the the ring to which it attacted [O—C—C—C torsion angle = −5.5 (3)°]. The three phenyl groups of the triphenylmethyl substituent are mutually nearly perpendicular, making dihedral angles of 89.87 (11) and 78.29 (11) and 60.34 (11)°. Two intramolecular C—H⋯ O hydrogen bonds occur. In the crystal, C—H⋯ O hydrogen bonds link the moleclues into chains along the b-axis direction. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685069/ /pubmed/23795088 http://dx.doi.org/10.1107/S1600536813012956 Text en © Pengying Zhao 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhao, Pengying 1-[2-(Trityloxy)phenyl]ethanone |
title | 1-[2-(Trityloxy)phenyl]ethanone |
title_full | 1-[2-(Trityloxy)phenyl]ethanone |
title_fullStr | 1-[2-(Trityloxy)phenyl]ethanone |
title_full_unstemmed | 1-[2-(Trityloxy)phenyl]ethanone |
title_short | 1-[2-(Trityloxy)phenyl]ethanone |
title_sort | 1-[2-(trityloxy)phenyl]ethanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685069/ https://www.ncbi.nlm.nih.gov/pubmed/23795088 http://dx.doi.org/10.1107/S1600536813012956 |
work_keys_str_mv | AT zhaopengying 12trityloxyphenylethanone |