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1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole

The title compound, C(21)H(23)NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with tri­methyl­silyl­acetyl­ene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244 (15) Å] and is oriented at a dihedral angle of 51.48 (4)° with respect to...

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Detalles Bibliográficos
Autores principales: Baglai, Iaroslav, Maraval, Valérie, Duhayon, Carine, Chauvin, Remi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685072/
https://www.ncbi.nlm.nih.gov/pubmed/23795091
http://dx.doi.org/10.1107/S1600536813012671
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author Baglai, Iaroslav
Maraval, Valérie
Duhayon, Carine
Chauvin, Remi
author_facet Baglai, Iaroslav
Maraval, Valérie
Duhayon, Carine
Chauvin, Remi
author_sort Baglai, Iaroslav
collection PubMed
description The title compound, C(21)H(23)NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with tri­methyl­silyl­acetyl­ene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244 (15) Å] and is oriented at a dihedral angle of 51.48 (4)° with respect to the phenyl ring. The supramolecular aggregation is completed by weak C—H⋯π inter­actions of the methylene and phenyl groups with the benzene and pyrrole rings of the indole ring system. The methyl groups of the tri­methyl­silyl unit are equally disordered over two sets of sites.
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spelling pubmed-36850722013-06-21 1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole Baglai, Iaroslav Maraval, Valérie Duhayon, Carine Chauvin, Remi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(23)NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with tri­methyl­silyl­acetyl­ene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244 (15) Å] and is oriented at a dihedral angle of 51.48 (4)° with respect to the phenyl ring. The supramolecular aggregation is completed by weak C—H⋯π inter­actions of the methylene and phenyl groups with the benzene and pyrrole rings of the indole ring system. The methyl groups of the tri­methyl­silyl unit are equally disordered over two sets of sites. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685072/ /pubmed/23795091 http://dx.doi.org/10.1107/S1600536813012671 Text en © Baglai et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Baglai, Iaroslav
Maraval, Valérie
Duhayon, Carine
Chauvin, Remi
1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole
title 1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole
title_full 1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole
title_fullStr 1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole
title_full_unstemmed 1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole
title_short 1-Ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1H-indole
title_sort 1-ethyl-2-phenyl-3-[2-(tri­methyl­sil­yl)ethyn­yl]-1h-indole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685072/
https://www.ncbi.nlm.nih.gov/pubmed/23795091
http://dx.doi.org/10.1107/S1600536813012671
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