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1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole
The title compound, C(21)H(23)NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with trimethylsilylacetylene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244 (15) Å] and is oriented at a dihedral angle of 51.48 (4)° with respect to...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685072/ https://www.ncbi.nlm.nih.gov/pubmed/23795091 http://dx.doi.org/10.1107/S1600536813012671 |
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author | Baglai, Iaroslav Maraval, Valérie Duhayon, Carine Chauvin, Remi |
author_facet | Baglai, Iaroslav Maraval, Valérie Duhayon, Carine Chauvin, Remi |
author_sort | Baglai, Iaroslav |
collection | PubMed |
description | The title compound, C(21)H(23)NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with trimethylsilylacetylene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244 (15) Å] and is oriented at a dihedral angle of 51.48 (4)° with respect to the phenyl ring. The supramolecular aggregation is completed by weak C—H⋯π interactions of the methylene and phenyl groups with the benzene and pyrrole rings of the indole ring system. The methyl groups of the trimethylsilyl unit are equally disordered over two sets of sites. |
format | Online Article Text |
id | pubmed-3685072 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36850722013-06-21 1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole Baglai, Iaroslav Maraval, Valérie Duhayon, Carine Chauvin, Remi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(23)NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with trimethylsilylacetylene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244 (15) Å] and is oriented at a dihedral angle of 51.48 (4)° with respect to the phenyl ring. The supramolecular aggregation is completed by weak C—H⋯π interactions of the methylene and phenyl groups with the benzene and pyrrole rings of the indole ring system. The methyl groups of the trimethylsilyl unit are equally disordered over two sets of sites. International Union of Crystallography 2013-05-18 /pmc/articles/PMC3685072/ /pubmed/23795091 http://dx.doi.org/10.1107/S1600536813012671 Text en © Baglai et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Baglai, Iaroslav Maraval, Valérie Duhayon, Carine Chauvin, Remi 1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole |
title | 1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole |
title_full | 1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole |
title_fullStr | 1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole |
title_full_unstemmed | 1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole |
title_short | 1-Ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1H-indole |
title_sort | 1-ethyl-2-phenyl-3-[2-(trimethylsilyl)ethynyl]-1h-indole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685072/ https://www.ncbi.nlm.nih.gov/pubmed/23795091 http://dx.doi.org/10.1107/S1600536813012671 |
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