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6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile
In the title compound, C(18)H(16)N(4), the dihedral angle between the benzene and phenyl rings is 61.40 (4)°. In the crystal, molecules are linked by N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers. The dimers are further linked by N—H⋯N(amine) hydrogen bonds, and both units are arranged al...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685078/ https://www.ncbi.nlm.nih.gov/pubmed/23795097 http://dx.doi.org/10.1107/S1600536813013342 |
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| author | Wang, Dao-Cai Song, Hang Yao, Shun |
| author_facet | Wang, Dao-Cai Song, Hang Yao, Shun |
| author_sort | Wang, Dao-Cai |
| collection | PubMed |
| description | In the title compound, C(18)H(16)N(4), the dihedral angle between the benzene and phenyl rings is 61.40 (4)°. In the crystal, molecules are linked by N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers. The dimers are further linked by N—H⋯N(amine) hydrogen bonds, and both units are arranged almost perpendicular to each other [angle between dimer mean planes = 84.43 (12)°]. This arrangement is extended to form a ladder-like structure parallel to the c axis. |
| format | Online Article Text |
| id | pubmed-3685078 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36850782013-06-21 6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile Wang, Dao-Cai Song, Hang Yao, Shun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)N(4), the dihedral angle between the benzene and phenyl rings is 61.40 (4)°. In the crystal, molecules are linked by N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers. The dimers are further linked by N—H⋯N(amine) hydrogen bonds, and both units are arranged almost perpendicular to each other [angle between dimer mean planes = 84.43 (12)°]. This arrangement is extended to form a ladder-like structure parallel to the c axis. International Union of Crystallography 2013-05-22 /pmc/articles/PMC3685078/ /pubmed/23795097 http://dx.doi.org/10.1107/S1600536813013342 Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Wang, Dao-Cai Song, Hang Yao, Shun 6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile |
| title | 6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile |
| title_full | 6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile |
| title_fullStr | 6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile |
| title_full_unstemmed | 6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile |
| title_short | 6-Amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile |
| title_sort | 6-amino-2-methyl-8-phenyl-1,2,3,4-tetrahydroisoquinoline-5,7-dicarbonitrile |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685078/ https://www.ncbi.nlm.nih.gov/pubmed/23795097 http://dx.doi.org/10.1107/S1600536813013342 |
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