tert-Butyl N-[(3R,4R)-1-(2-cyano­acet­yl)-4-methyl­piperidin-3-yl]-N-methyl­carbamate

The piperidine ring of the title compound, C(15)H(25)N(3)O(3), adopts a slightly distorted chair conformation with the cis substituents displaying an N—C—C—C torsion angle of 43.0 (3)°. The cyano group (plane defined by C—C—C N atoms) is bent slightly out of the plane of the amide group by 13.3 (2)°...

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Detalles Bibliográficos
Autores principales: Gehringer, Matthias, Forster, Michael, Schollmeyer, Dieter, Laufer, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685082/
https://www.ncbi.nlm.nih.gov/pubmed/23795101
http://dx.doi.org/10.1107/S1600536813013512
Descripción
Sumario:The piperidine ring of the title compound, C(15)H(25)N(3)O(3), adopts a slightly distorted chair conformation with the cis substituents displaying an N—C—C—C torsion angle of 43.0 (3)°. The cyano group (plane defined by C—C—C N atoms) is bent slightly out of the plane of the amide group by 13.3 (2)°. The carbamate group is oriented at a dihedral angle of 60.3 (5)° relative to the amide group.

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