5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one

In the title compound, C(7)H(12)N(2)OS, the 2-sulfanylideneimidazolidin-4-one moiety is nearly planar, with a maximum deviation of 0.054 (2) Å. In the crystal, a pair of N—H⋯O hydrogen bonds and a pair of N—H⋯S hydrogen bonds each form a centrosymmetric ring with an R (2) (2)(8) graph-set motif. The...

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Autores principales: Ichitani, Masaki, Kitoh, Soh-ichi, Fujinami, Shuhei, Suda, Mitsuhiro, Honda, Mitsunori, Kunimoto, Ko-Ki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685094/
https://www.ncbi.nlm.nih.gov/pubmed/23795113
http://dx.doi.org/10.1107/S1600536813013639
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author Ichitani, Masaki
Kitoh, Soh-ichi
Fujinami, Shuhei
Suda, Mitsuhiro
Honda, Mitsunori
Kunimoto, Ko-Ki
author_facet Ichitani, Masaki
Kitoh, Soh-ichi
Fujinami, Shuhei
Suda, Mitsuhiro
Honda, Mitsunori
Kunimoto, Ko-Ki
author_sort Ichitani, Masaki
collection PubMed
description In the title compound, C(7)H(12)N(2)OS, the 2-sulfanylideneimidazolidin-4-one moiety is nearly planar, with a maximum deviation of 0.054 (2) Å. In the crystal, a pair of N—H⋯O hydrogen bonds and a pair of N—H⋯S hydrogen bonds each form a centrosymmetric ring with an R (2) (2)(8) graph-set motif. The enanti­omeric R and S mol­ecules are alternately linked into a tape along [1-10] via these pairs of hydrogen bonds.
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spelling pubmed-36850942013-06-21 5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one Ichitani, Masaki Kitoh, Soh-ichi Fujinami, Shuhei Suda, Mitsuhiro Honda, Mitsunori Kunimoto, Ko-Ki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(12)N(2)OS, the 2-sulfanylideneimidazolidin-4-one moiety is nearly planar, with a maximum deviation of 0.054 (2) Å. In the crystal, a pair of N—H⋯O hydrogen bonds and a pair of N—H⋯S hydrogen bonds each form a centrosymmetric ring with an R (2) (2)(8) graph-set motif. The enanti­omeric R and S mol­ecules are alternately linked into a tape along [1-10] via these pairs of hydrogen bonds. International Union of Crystallography 2013-05-25 /pmc/articles/PMC3685094/ /pubmed/23795113 http://dx.doi.org/10.1107/S1600536813013639 Text en © Ichitani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ichitani, Masaki
Kitoh, Soh-ichi
Fujinami, Shuhei
Suda, Mitsuhiro
Honda, Mitsunori
Kunimoto, Ko-Ki
5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one
title 5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one
title_full 5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one
title_fullStr 5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one
title_full_unstemmed 5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one
title_short 5-Isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one
title_sort 5-isopropyl-5-methyl-2-sulfanylidene­imidazolidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685094/
https://www.ncbi.nlm.nih.gov/pubmed/23795113
http://dx.doi.org/10.1107/S1600536813013639
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