2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine

In the title compound, C(23)H(22)BrNO, the cyclo­heptane ring adopts a chair conformation. The pyridine ring makes dihedral angles of 58.63 (15) and 8.27 (16)° with the benzene rings. The dihedral angle between the benzene rings is 56.68 (17)°. The crystal packing features C—Br⋯π inter­actions [Br⋯c...

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Autores principales: Çelik, Ísmail, Akkurt, Mehmet, Gezegen, Hayreddin, Kazak, Canan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685096/
https://www.ncbi.nlm.nih.gov/pubmed/23795115
http://dx.doi.org/10.1107/S1600536813013913
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author Çelik, Ísmail
Akkurt, Mehmet
Gezegen, Hayreddin
Kazak, Canan
author_facet Çelik, Ísmail
Akkurt, Mehmet
Gezegen, Hayreddin
Kazak, Canan
author_sort Çelik, Ísmail
collection PubMed
description In the title compound, C(23)H(22)BrNO, the cyclo­heptane ring adopts a chair conformation. The pyridine ring makes dihedral angles of 58.63 (15) and 8.27 (16)° with the benzene rings. The dihedral angle between the benzene rings is 56.68 (17)°. The crystal packing features C—Br⋯π inter­actions [Br⋯centroid distances= 3.813 (2) and 3.839 (2) Å; C—Br⋯centroid = 126.25 (10) and 138.31 (10)°, respectively, forming a three dimensional supramolecular architecture.
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spelling pubmed-36850962013-06-21 2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine Çelik, Ísmail Akkurt, Mehmet Gezegen, Hayreddin Kazak, Canan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(22)BrNO, the cyclo­heptane ring adopts a chair conformation. The pyridine ring makes dihedral angles of 58.63 (15) and 8.27 (16)° with the benzene rings. The dihedral angle between the benzene rings is 56.68 (17)°. The crystal packing features C—Br⋯π inter­actions [Br⋯centroid distances= 3.813 (2) and 3.839 (2) Å; C—Br⋯centroid = 126.25 (10) and 138.31 (10)°, respectively, forming a three dimensional supramolecular architecture. International Union of Crystallography 2013-05-25 /pmc/articles/PMC3685096/ /pubmed/23795115 http://dx.doi.org/10.1107/S1600536813013913 Text en © Çelik et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Çelik, Ísmail
Akkurt, Mehmet
Gezegen, Hayreddin
Kazak, Canan
2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine
title 2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine
title_full 2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine
title_fullStr 2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine
title_full_unstemmed 2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine
title_short 2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine
title_sort 2-(4-bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5h-cyclo­hepta­[b]pyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685096/
https://www.ncbi.nlm.nih.gov/pubmed/23795115
http://dx.doi.org/10.1107/S1600536813013913
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