2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate

The title compound, C(15)H(18)NO(3)PS·C(6)H(6), is a rare example of a crystallographically characterized exocyclic phosphiniminium–arene­sulfonate zwitterion, which crystallises as its benzene solvate. The crystal structure shows that the N atom is protonated and that the iminium H atom forms both...

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Detalles Bibliográficos
Autores principales: Burns, Christopher T., Shang, Suisheng, Mashuta, Mark S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685103/
https://www.ncbi.nlm.nih.gov/pubmed/23795122
http://dx.doi.org/10.1107/S1600536813013755
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author Burns, Christopher T.
Shang, Suisheng
Mashuta, Mark S.
author_facet Burns, Christopher T.
Shang, Suisheng
Mashuta, Mark S.
author_sort Burns, Christopher T.
collection PubMed
description The title compound, C(15)H(18)NO(3)PS·C(6)H(6), is a rare example of a crystallographically characterized exocyclic phosphiniminium–arene­sulfonate zwitterion, which crystallises as its benzene solvate. The crystal structure shows that the N atom is protonated and that the iminium H atom forms both intra- and inter­molecular hydrogen bonds to the single-bonded sulfonate O atom in an R (2) (2)(4) graph-set motif. The dihedral angle between the aromatic rings in the main molecule is 89.49 (8)°.
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spelling pubmed-36851032013-06-21 2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate Burns, Christopher T. Shang, Suisheng Mashuta, Mark S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(18)NO(3)PS·C(6)H(6), is a rare example of a crystallographically characterized exocyclic phosphiniminium–arene­sulfonate zwitterion, which crystallises as its benzene solvate. The crystal structure shows that the N atom is protonated and that the iminium H atom forms both intra- and inter­molecular hydrogen bonds to the single-bonded sulfonate O atom in an R (2) (2)(4) graph-set motif. The dihedral angle between the aromatic rings in the main molecule is 89.49 (8)°. International Union of Crystallography 2013-05-25 /pmc/articles/PMC3685103/ /pubmed/23795122 http://dx.doi.org/10.1107/S1600536813013755 Text en © Burns et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Burns, Christopher T.
Shang, Suisheng
Mashuta, Mark S.
2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate
title 2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate
title_full 2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate
title_fullStr 2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate
title_full_unstemmed 2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate
title_short 2-[(Di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate
title_sort 2-[(di­methyl­phenyl­phosphanyl­idene)aza­nium­yl]-5-methyl­benzene­sulfonate benzene monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685103/
https://www.ncbi.nlm.nih.gov/pubmed/23795122
http://dx.doi.org/10.1107/S1600536813013755
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AT mashutamarks 2dimethylphenylphosphanylideneazaniumyl5methylbenzenesulfonatebenzenemonosolvate

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