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N-[(2,6-Diethylphenyl)carbamothioyl]-2,2-diphenylacetamide
In the title compound, C(25)H(26)N(2)OS, the diethyl-substituted benzene ring forms dihedral angles of 67.38 (9) and 55.32 (9)° with the terminal benzene rings. The molecule adopts a trans–cis conformation with respect to the orientations of the diphenylmethane and 1,3-diethylbenzene groups wit...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685105/ https://www.ncbi.nlm.nih.gov/pubmed/23795124 http://dx.doi.org/10.1107/S1600536813013354 |
Sumario: | In the title compound, C(25)H(26)N(2)OS, the diethyl-substituted benzene ring forms dihedral angles of 67.38 (9) and 55.32 (9)° with the terminal benzene rings. The molecule adopts a trans–cis conformation with respect to the orientations of the diphenylmethane and 1,3-diethylbenzene groups with respect to the S atom across the C—N bonds. This conformation is stabilized by an intramolecular N—H⋯O hydrogen bond, which generates an S(6) ring. In the crystal, pairs of N—H⋯S hydrogen bonds link the molecules into inversion dimers, forming R (2) (2)(6) loops. The dimer linkage is reinforced by a pair of C—H⋯S hydrogen bonds, which generate R (2) (2)(8) loops. Weak C—H⋯π and π–π [centroid–centroid seperation = 3.8821 (10) Å] interactions also occur in the crystal structure. |
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