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6-(4-Methylphenyl)-1,3,5-triazine-2,4-diamine–4-methylbenzoic acid (1/1)
The 4-methylbenzoic acid molecule of the title adduct, C(10)H(11)N(5)·C(8)H(8)O(2), is approximately planar with a dihedral angle of 6.3 (2)° between the carboxylic acid group and the benzene ring. In the triazine molecule, the plane of the triazine ring makes a dihedral angle of 29.2 (2)° with...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685107/ https://www.ncbi.nlm.nih.gov/pubmed/23795126 http://dx.doi.org/10.1107/S1600536813013895 |
Sumario: | The 4-methylbenzoic acid molecule of the title adduct, C(10)H(11)N(5)·C(8)H(8)O(2), is approximately planar with a dihedral angle of 6.3 (2)° between the carboxylic acid group and the benzene ring. In the triazine molecule, the plane of the triazine ring makes a dihedral angle of 29.2 (2)° with that of the adjacent benzene ring. In the crystal, the acid and base molecules are linked via N—H⋯O and O—H⋯N hydrogen bonds with an R (2) (2)(8) motif, and the acid–base pairs are further connected via N—H⋯N hydrogen bonds with R (2) (2)(8) motifs, forming a supramolecular ribbon along [101]. Between the tapes, a weak C—H⋯π interaction is observed. |
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