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6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)

The 4-methyl­benzoic acid mol­ecule of the title adduct, C(10)H(11)N(5)·C(8)H(8)O(2), is approximately planar with a dihedral angle of 6.3 (2)° between the carb­oxy­lic acid group and the benzene ring. In the triazine mol­ecule, the plane of the triazine ring makes a dihedral angle of 29.2 (2)° with...

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Autores principales: Thanigaimani, Kaliyaperumal, Arshad, Suhana, Razak, Ibrahim Abdul, Makeshvaran, Duraisamy, Balasubramani, Kasthuri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685107/
https://www.ncbi.nlm.nih.gov/pubmed/23795126
http://dx.doi.org/10.1107/S1600536813013895
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author Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
Makeshvaran, Duraisamy
Balasubramani, Kasthuri
author_facet Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
Makeshvaran, Duraisamy
Balasubramani, Kasthuri
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description The 4-methyl­benzoic acid mol­ecule of the title adduct, C(10)H(11)N(5)·C(8)H(8)O(2), is approximately planar with a dihedral angle of 6.3 (2)° between the carb­oxy­lic acid group and the benzene ring. In the triazine mol­ecule, the plane of the triazine ring makes a dihedral angle of 29.2 (2)° with that of the adjacent benzene ring. In the crystal, the acid and base mol­ecules are linked via N—H⋯O and O—H⋯N hydrogen bonds with an R (2) (2)(8) motif, and the acid–base pairs are further connected via N—H⋯N hydrogen bonds with R (2) (2)(8) motifs, forming a supra­molecular ribbon along [101]. Between the tapes, a weak C—H⋯π inter­action is observed.
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spelling pubmed-36851072013-06-21 6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1) Thanigaimani, Kaliyaperumal Arshad, Suhana Razak, Ibrahim Abdul Makeshvaran, Duraisamy Balasubramani, Kasthuri Acta Crystallogr Sect E Struct Rep Online Organic Papers The 4-methyl­benzoic acid mol­ecule of the title adduct, C(10)H(11)N(5)·C(8)H(8)O(2), is approximately planar with a dihedral angle of 6.3 (2)° between the carb­oxy­lic acid group and the benzene ring. In the triazine mol­ecule, the plane of the triazine ring makes a dihedral angle of 29.2 (2)° with that of the adjacent benzene ring. In the crystal, the acid and base mol­ecules are linked via N—H⋯O and O—H⋯N hydrogen bonds with an R (2) (2)(8) motif, and the acid–base pairs are further connected via N—H⋯N hydrogen bonds with R (2) (2)(8) motifs, forming a supra­molecular ribbon along [101]. Between the tapes, a weak C—H⋯π inter­action is observed. International Union of Crystallography 2013-05-25 /pmc/articles/PMC3685107/ /pubmed/23795126 http://dx.doi.org/10.1107/S1600536813013895 Text en © Thanigaimani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
Makeshvaran, Duraisamy
Balasubramani, Kasthuri
6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)
title 6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)
title_full 6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)
title_fullStr 6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)
title_full_unstemmed 6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)
title_short 6-(4-Methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)
title_sort 6-(4-methyl­phen­yl)-1,3,5-triazine-2,4-di­amine–4-methyl­benzoic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685107/
https://www.ncbi.nlm.nih.gov/pubmed/23795126
http://dx.doi.org/10.1107/S1600536813013895
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